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Dokumentenidentifikation EP0978853 06.04.2006
EP-Veröffentlichungsnummer 0000978853
Titel Reduktionswiderstandsfähige dielektrische keramische Zusammensetzung und diese beinhaltender monolitischer keramischer Kondensator
Anmelder Murata Manufacturing Co., Ltd., Nagaokakyo, Kyoto, JP
Erfinder Sakamoto, Norihiko, Nagaokakyo-shi, Kyoto-fu 617-8555, JP;
Motoki, Tomoo, Nagaokakyo-shi, Kyoto-fu 617-8555, JP;
Sano, Harunobu, Nagaokakyo-shi, Kyoto-fu 617-8555, JP
Vertreter Rechts- und Patentanwälte Lorenz Seidler Gossel, 80538 München
DE-Aktenzeichen 69929378
Vertragsstaaten DE, FR, GB
Sprache des Dokument EN
EP-Anmeldetag 04.08.1999
EP-Aktenzeichen 991154154
EP-Offenlegungsdatum 09.02.2000
EP date of grant 11.01.2006
Veröffentlichungstag im Patentblatt 06.04.2006
IPC-Hauptklasse H01G 4/12(2006.01)A, F, I, 20051017, B, H, EP
IPC-Nebenklasse C04B 35/465(2006.01)A, L, I, 20051017, B, H, EP   C04B 35/47(2006.01)A, L, I, 20051017, B, H, EP   

Beschreibung[en]
BACKGROUND OF THE INVENTION 1. Field of the Invention

The present invention relates to a anti-reducing dielectric ceramic composition and a monolithic ceramic capacitor using the dielectric ceramic composition.

2. Description of the Related Art

When a dielectric material mainly containing a titanate is used to form a monolithic ceramic capacitor, there has been a problem that such a dielectric material is sintered under a condition of a low concentration oxygen partial pressure (neutral or reductive atmosphere), the dielectric material is undesirably reduced and hence undesirably becomes a semi-conductor. Because of this, in order to form internal electrodes, it is necessary to employ a noble metal such as palladium and platinum which will not be melted even under a sintering temperature for sintering a dielectric ceramic material, nor will it cause the dielectric ceramic material to be converted to a semi-conductor and itself be oxidized under a high concentration oxygen partial pressure. As a result, it is difficult to manufacture a monolithic ceramic capacitor with a low cost.

Accordingly, in order to solve the problems, it is usually desired to use, as an internal electrode material, inexpensive base metals such as nickel and copper. However, when such kind of base metal is used as an internal electrode material and is sintered under a conventional condition, said electrode material is oxidized. As a result, it is impossible to provide a desired function as an electrode. For this reason, in order for such kind of base metal to be used as an internal electrode material, it is necessary to employ a dielectric material having an excellent dielectric property, with its ceramic layer having a resistance of not becoming a semiconductor even under a condition of a neutral or reductive atmosphere having a low concentration oxygen partial pressure. In order to meet such a requirement, Japanese laid-open patent application Nos. 63-289707 and 63-224106 suggests an improved dielectric material which is (Cal-xSrx)(Zrl-yTiy)O3 composition. By using such kind of improved dielectric material, it has become possible to obtain a dielectric ceramic which is not converted into a semiconductor even when being sintered in a reductive atmosphere, thereby rendering it possible to manufacture a monolithic ceramic capacitor using a base metal material such as nickel or copper for forming internal electrode.

However, with the anti-reducing dielectric ceramic composition disclosed in the above Japanese laid-open patent application No. 63-289707, there is a problem that although it has excellent capacity and temperature characteristics, its dielectric constant is as low as 46. On the other hand, with the anti-reducing dielectric ceramic composition disclosed in the above Japanese laid-open patent application No. 63-224106, there is a problem that if an thickness of laminated ceramic body is made to be quite thin for the purpose of producing a monolithic ceramic capacitor compact in size but large in its capacity, it is difficult to ensure a desired reliability during a life measuring test under a high temperature load.

SUMMARY OF THE INVENTION

The present provides an improved anti-reducing dielectric ceramic composition having a dielectric constant of 100 or higher and an excellent reliability during a life test under a high temperature load, and provides a monolithic ceramic capacitor formed by using the improved anti-reducing dielectric ceramic composition.

In accordance with one aspect of the present invention, a anti-reducing dielectric ceramic composition comprises a composite oxide containing as metal elements M (M: Ca, or Ca and Sr), Zr and Ti, when represented by a composition formula (Ca1-xSrx)m(Zr1-yTiy)O3, the values of x, y, and m satisfy the ranges of 0 ≤ x < 0.5, 0.60 < y ≤ 0.85, 0.85 < m < 1.30 so as to form a main component, every 100 mols of the main component is mixed with at least one of a manganese compound and a magnesium compound incorporated as an accessory component in a range of 0.1 to 6 mols in terms of MnO and MgO respectively.

The composition may further contain a sintering aid agent.

The sintering aid agent may preferably contain at least one of Si and B.

Further, the sintering aid agent may be SiO2.

Moreover, the sintering aid agent may be Li2O-(Si, Ti)O2-MO series (where MO is at least one of Al2O3 and ZrO2).

In addition, the sintering aid agent may be SiO2-TiO2-XO series (where XO is at least one substance selected from a group consisting of BaO, SrO, CaO, MgO, ZnO and MnO). Preferably, the agent contains at least one substance selected from Al2O3 and ZrO2.

Further, the sintering aid agent may be Li2O-B2O3-(Si, Ti)O2 series. Preferably, the sintering aid agent contains at least one substance selected from Al2O3 and ZrO2.

Moreover, the agent may be B2O3-Al2O3-XO series (where XO is at least one substance selected from a group consisting of BaO, SrO, CaO, MgO, ZnO and MnO).

The content of the agent may be 20 parts by weight or lower with respect to 100 parts by weight in total of the main component and the accessory component.

A monolithic ceramic capacitor of the present invention includes a plurality of dielectric ceramic layers, internal electrodes formed between the dielectric ceramic layers, external electrodes electrically connected with the internal electrodes, characterized in that the dielectric ceramic layers are made of the above dielectric ceramic compositions, each of the internal electrodes contains a base metal as its main component.

The base metal may preferably be nickel or copper.

BRIEF DESCRIPTION OF THE DRAWINGS

  • Fig. 1 is a cross sectional view showing a monolithic ceramic capacitor according to the present invention.
  • Fig. 2 is a plan view of a ceramic green sheet according to the present invention.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

Preferred embodiments of the present invention will be described in accordance with several working examples.

(Example 1)

At first, SrCO3, CaCO3, ZrO2, TiO2, MnCO3 and MgCO3 powders each having a purity of 99% or more were prepared as starting materials.

Then, powders of SrCO3, CaCO3, ZrO2, TiO2 were weight and mixed to obtain a raw material of a main component represented by a formula (Ca1-xSrx)m(Zr1-yTiy)O3 where x, y and m are indicated in Table 1. Further, MnCO3 and MgCO3 were weighed and mixed with the above mixture of SrCO3, CaCO3, ZrO2, TiO2 to obtain a starting material such that the MnCO3 and MgCO3 serve as raw material of accessory components consisting of w mols of MnO and z mols of MgO (shown in Table 1) with respect to 100 mols of the main component. Then, the starting material was put into a ball mill and wet-milled therein, followed by being calcined in air at 1000 to 1200°C for two hours, thereby obtaining a calcined powder. In the following Table 1, marks * are used to represent ranges other than those of the present invention, while those without marks * are used to represent the ranges of the present invention. Table 1 Sample No. x Y m w z *1 0.50 0.70 1.00 3.0 1.0 *2 0.20 0.60 0.90 1.0 0 *3 0.30 0.90 1.20 2.0 2.0 *4 0.15 0.65 0.85 0 1.0 *5 0.40 0.85 1.30 0.5 1.5 *6 0.20 0.70 1.10 0 0 *7 0 0.65 1.00 7.0 0 *8 0.10 0.80 0.95 0 7.0 *9 0.30 0.75 1.25 3.0 4.0 10 0 0.85 0.90 0.0 0.1 11 0.45 0.65 1.20 4.0 1.0 12 0.20 0.70 0.90 0 6.0 13 0.15 0.80 1.25 3.0 3.0 14 0 0.75 1.10 0.1 0 15 0.35 0.80 1.00 6.0 0 Mark * is used to represent a range other than the present invention.

Next, some organic solvent such as polyvinylbutyl based binder and ethanol were added in the calcined powder, and were wet-milled sufficiently in a ball mill, thereby obtaining a ceramic slurry. Subsequently, the ceramic slurry is formed into a plurality of sheets with the use of doctor blade method, thereby obtaining a plurality of green sheets 2b each having a rectangular shape and a thickness of 10 µm. After that, an electrically conductive paste 4 mainly containing Ni was printed onto the ceramic green sheets, thus producing electrically conductive paste layers which will then serve as internal electrodes.

Further, a plurality of the ceramic green sheets, on which the electrically conductive paste layers have been formed, were laminated together in a manner such that edge portions thereof are arranged alternatively on the side where the electrically conductive paste players have been pulled out, thereby obtaining a desired laminated body. The obtained laminated body was then heated to a temperature of 350°C in an atmosphere of N2 so as to decompose the binder, followed by firing in a reductive atmosphere consisting of H2-N2-H2O gas, thereby obtaining a sintered ceramic body.

After firing, a silver paste 5 was applied to two opposite end faces of the obtained ceramic sintered body, followed by baking treatment in N2 atmosphere at 600°C, thereby forming external electrodes which are electrically connected with the internal electrodes. Afterwards, a Ni-plating film 6 is formed on the external electrodes, followed by forming a solder-plating film on said Ni-plating film 7.

The monolithic ceramic capacitor 1 has a width of 1.6 mm, a length of 3.2 mm, and a thickness of 1.2 mm, with the thickness of the dielectric ceramic layer 2a being 6 µm. Further, the monolithic ceramic capacitor 1 had 150 pieces of effective dielectric ceramic layers 2a in all.

Thereafter, the electric property of the monolithic ceramic capacitor 1 was measured, thus obtaining an electrostatic capacity and a dielectric loss (tan &dgr;) under a condition of 1 KHz, 1 Vrms and 25°C, thereby calculating a dielectric constant (&egr;) from the electrostatic capacity. Subsequently, D. C. voltage of 25 v was continuously applied to the capacitor under a temperature of 25°C for 2 minutes, thereby measuring insulating resistance and thus calculating a specific resistance.

Further, under a condition of 1 KHz and 1 Vrms, a variation of the electrostatic capacity with a temperature change was measured, and its rate of change was measured in accordance with the following equation. TC (ppm/°C)={(ϵ85°C-ϵ20°C)/ϵ20°C}×{1/(85°C-20°C)}×100

Moreover, in a life test under a high temperature load, samples each including 36 pieces were used and D. C. voltage of 150 V was applied to these samples under a temperature of 150°C, thereby measuring a variation of an insulating resistance with the passing of time. On the other hand, during such a test, a time period necessary for the insulating resistance of each sample to become 106 Q or lower was deemed as a life time, thereby obtaining an average life time.

The results of the evaluation are shown in Table 2. Table 2 Sample No. Sintering temperature (°C) Dielectric constant Dielectric loss (%) TC (ppm/°C) Specific resistance (&OHgr;·cm) Average life (hrs) *1 1300 180 0.05 -1200 >1013 20 *2 1350 70 0.06 -800 >1013 120 *3 1270 140 0.07 -1000 >1013 10 *4 1250 110 1.00 -750 >1013 5 *5 1350 Not sintered *6 1350 Not sintered *7 1300 150 0.03 -2000 >1013 50 *8 1350 120 0.09 -1500 >1013 80 *9 1270 105 0.07 -1800 >1013 70 10 1300 110 0.05 -800 >1013 150 11 1270 140 0.10 -1000 >1013 60 12 1270 100 0.08 -850 >1013 70 13 1320 110 0.06 -950 >1013 90 14 1300 120 0.05 -750 >1013 120 15 1270 100 0.07 -800 >1013 110 Mark * is used to represent a range other than the present invention.

As understood from Table 2, the monolithic ceramic capacitor obtained by using the anti-reducing dielectric ceramic composition of the present invention has a dielectric constant of 100 or higher, a dielectric loss of 0.1% or lower, and its change rate in electrostatic capacity with a temperature change (TC) is as small as 1000 ppm/°C. Moreover, during a life test under a high temperature load, D. C. voltage of 150 V was applied under a temperature of 150°C, and it was found that an average life time was as long as 50 hours or longer.

Here, an explanation will be given to a reason as to why the composition of the present invention should be limited to the above values.

With respect to the composition formula (Cal-xSrx)m(Zrl-yTiy)O3 (0 ≤ x < 0.5, 0.60 < y ≤ 0.85, 0.85 < m < 1.30), if, as in a case of sample No. 1, the value of x is 0.5 or higher, the change rate in electrostatic capacity with a temperature change (TC) will become large, thus its average life will become short. For this reason, it is preferred that the amount of Sr should be controlled within a range of 0 ≤ x < 0.5.

If, as in a case of sample No. 2, the value of y is 0.6 or lower, its dielectric constant will decrease. On the other hand, if, as in a case of sample No. 3, the value of y is larger than 0.85, an average life will become short. For this reason, it is preferred that the amount of Ti should be controlled within a range of 0.60 < y ≤ 0.85.

Further, if, as in a case of sample No. 4, the value of m is 0.85 or lower, a dielectric loss will become large and an average life will become short. On the other hand, if, as in a case of sample No. 5, the value of m is 1.30 or higher, a sinterability will become extremely bad. For this reason, it is preferred that the amount of m should be controlled within a range of 0.85 < m < 1.30.

Moreover, if, as in a case of sample No. 6, when a content of at least one of MnO and MgO is below 0.1 mol, a sinterability will become extremely bad. On the other hand, if, as in the cases of sample Nos. 7 to 9, when a content of at least one of MnO and MgO is over 6 mols, the change rate in electrostatic capacity with a temperature change (TC) will become large. For this reason, it is preferred that a manganese compound and a magnesium compound, which are incorporated as an accessory component, should be controlled within a range of 0.1 to 6 mols with respect to 100 mols of the above main component, by calculatively converting the manganese compound into MnO and the magnesium compound into MgO.

(Example 2)

At first, SrCO3, CaCO3, ZrO2, TiO2, MnCO3 and MgCO3 powders each having a purity of 99% or more were prepared in order to be used as start materials.

Then, the above start material powders were taken by weighing the weights thereof, so as to form a composition which can be represented by (Ca0.8Sr0.2)1.05(Zr0.3Ti0.7)O3. Then, the prepared start material powders were put into a boll mill and wet-milled therein, followed by being calcined in air at 1000 to 1200°C for two hours, thereby obtaining a calcined powder material. Further, other start materials which are MnCO3 and MgCO3 were taken by weighing the weights thereof and were mixed with the above main component so as to obtain start material powder, such that the start materials MnCO3 and MgCO3 are used as an accessory component consisting of 0.5 mols of MnO and 1.0 mols of MgO with respect to 100 mols of the main component. Further, sintering aid agents shown in Table 3, were mixed with the start material powders in a predetermined amount. However, the sintering agents, were added in the amounts (parts by weight) with respect to 100 parts by weight in all of the above main component and the accessory component. Table 3 Sample No. Sintering aid agent (mole ratio) Added amount (parts by weight) 21 0.35Li2O-0.50B2O3-0.15(0.90Si-0.10Ti)O2 25 22 SiO2 5 23 0.25Li2O-0.65(0.30Si-0.70Ti)O2-0.10Al2O3 1 24 0.66SiO2-0.17TiO2-0.15BaO-0.02MnO 0.1 25 0.45SiO2-0.22TiO2-0.28BaO-0.05Al2O3 10 26 0.35Li2O-0.50B2O3-0.15(0.90Si-0.10Ti)O2 3 27 0.35Li2O-0.15B2O3-0.45(0.30Si-0.70Ti)O2-0.05ZrO2 6 28 0.70B2O3-0.15Al2O3-0.10BaO-0.03ZnO-0.02MnO 20

With the use of the above start material powders, a monolithic ceramic capacitor was prepared and its electric property was measured using the same method as in Example 1, with the measured results shown in the following Table 4. Table 4 Sample No. Sintering temperature (°C) Dielectric constant Dielectric loss (%) TC (ppm/°C) Specific resistance (&OHgr;·cm) Average life (hrs) 21 950 100 1.50 -900 >1013 20 22 1100 110 0.05 -830 >1013 80 23 1150 110 0.06 -850 >1013 90 24 1150 120 0.05 -900 >1013 60 25 1050 100 0.08 -810 >1013 55 26 1070 120 0.08 -880 >1013 100 27 980 110 0.07 -780 >1013 75 28 950 100 0.10 -950 >1013 50

As understood from the cases of sample Nos. 22 to 28 in the Table 4, the monolithic ceramic capacitor obtained by using the anti-reducing dielectric ceramic composition of the present invention has a dielectric constant of 100 or higher, a dielectric loss of 0.1% or lower, and its change rate in electrostatic capacity with a temperature change (TC) is as small as 1000 ppm/°C or lower (an absolute value). Moreover, during a life test under a high temperature load, D. C. voltage of 150 V was applied under a temperature of 150°C, and it was found that an average life was as long as 50 hours or longer. In addition, by incorporating the sintering auxiliary materials, it is possible to conduct the sintering treatment at a temperature of 1150°C or lower. On the other hand, if the content of a sintering auxiliary material is larger than 20 parts by weight, the dielectric loss will become large as in a case of sample No. 21, and its average life will become short. For this reason, it is preferred that the content of a sintering auxiliary material be controlled at 20 parts by weight or lower, with respect to 100 parts by weight of the main component and the accessory component.

As can be clearly understood from the above description, the monolithic ceramic capacitor formed by using the dielectric ceramic composition of the present invention, has a dielectric constant of 100 or higher and an excellent reliability during the life measuring test under a high temperature load. Therefore, the dielectric ceramic composition of the present invention can be used as a condenser material for temperature compensation, and can be used as a dielectric resonator material for microwave, thereby ensuring a high value for industrial use.


Anspruch[de]
Reduzierfeste dielektrische keramische Zusammensetzung, die die Metallelemente M (M: Ca oder Ca und Sr), Zr und Ti umfaßt, wenn dargestellt durch eine Formel (Ca1-xSrx)m(Zr1-yTiy)O3, wobei die Werte von x, y und m den folgenden Bereichen genügen

0 ≤ x < 0,5

0,60 < y ≤ 0,85

0,85 < m < 1,30

um eine Hauptkomponente auszubilden, alle 100 mol der Hauptkomponente mit mindestens einer Manganverbindung und einer Magnesiumverbindung gemischt werden, eingearbeitet als eine Zusatzkomponente in einem Bereich von 0,1 bis 6 mol hinsichtlich MnO bzw. MgO.
Reduzierfeste dielektrische keramische Zusammensetzung nach Anspruch 1, wobei die Zusammensetzung weiterhin ein Sinterhilfsmittel enthält. Reduzierfeste dielektrische keramische Zusammensetzung nach Anspruch 2, wobei das Mittel mindestens Si oder B enthält. Reduzierfeste dielektrische keramische Zusammensetzung nach Anspruch 2, wobei das Mittel SiO2 ist. Reduzierfeste dielektrische keramische Zusammensetzung nach Anspruch 2, wobei das Mittel Li2O-(Si, Ti)O2-MO-Serie ist (wobei MO mindestens Al2O3 oder ZrO2 ist). Reduzierfeste dielektrische keramische Zusammensetzung nach Anspruch 2, wobei das Mittel SiO2-TiO2-XO-Serie ist (wobei XO mindestens eine Substanz ist ausgewählt aus einer Gruppe bestehend aus BaO, SrO, CaO, MgO, ZnO und MnO). Reduzierfeste dielektrische keramische Zusammensetzung nach Anspruch 6, wobei das Mittel mindestens eine Substanz ausgewählt unter Al2O3 und ZrO2 enthält. Reduzierfeste dielektrische keramische Zusammensetzung nach Anspruch 2, wobei das Mittel Li2OB2O3-(Si, Ti)O2-Serie ist. Reduzierfeste dielektrische keramische Zusammensetzung nach Anspruch 8, wobei das Mittel mindestens eine Substanz ausgewählt unter Al2O3 und ZrO2 enthält. Reduzierfeste dielektrische keramische Zusammensetzung nach Anspruch 2, wobei das Mittel B2O3-Al2O3-XO-Serie ist (wobei XO mindestens eine Substanz ist ausgewählt aus einer Gruppe bestehend aus BaO, SrO, CaO, MgO, ZnO und MnO). Reduzierfeste dielektrische keramische Zusammensetzung nach einem der Ansprüche 2 bis 10, wobei der Gehalt an dem Mittel höchstens 20 Gewichtsteile bezogen auf insgesamt 100 Gewichtsteile der Hauptkomponente und der Zusatzkomponente beträgt. Monolithischer Keramikkondensator mit mehreren dielektrischen Keramikschichten, zwischen den dielektrischen Keramikschichten ausgebildeten Innenelektroden, mit den Innenelektroden elektrisch verbundenen Außenelektroden, dadurch gekennzeichnet, daß die dielektrischen Keramikschichten aus einer in einem der Ansprüche 1 bis 11 aufgeführten dielektrischen keramischen Zusammensetzung hergestellt sind, wobei jede der Innenelektroden ein Basismetall als seine Hauptkomponente enthält. Monolithischer Keramikkondensator nach Anspruch 12, wobei das Basismetall Nickel oder Kupfer ist.
Anspruch[en]
A anti-reducing dielectric ceramic composition comprising metal elements M (M: Ca, or Ca and Sr), Zr and Ti, when represented by a formula (Ca1-xSrx)m(Zr1-yTiy)O3, where the values of x, y, and m satisfy the ranges of

0 ≤ x < 0.5

0.60 < y ≤ 0.85

0.85 < m < 1.30

so as to form a main component, every 100 mols of the main component is mixed with at least one of a manganese compound and a magnesium compound incorporated as an accessory component in a range of 0.1 to 6 mols in terms of MnO and MgO respectively.
The anti-reducing dielectric ceramic composition according to claim 1, wherein said composition further contains a sintering aid agent. The anti-reducing dielectric ceramic composition according to claim 2, wherein said agent contains at least one of Si and B. The anti-reducing dielectric ceramic composition according to claim 2, wherein said agent is SiO2. The anti-reducing dielectric ceramic composition according to claim 2, wherein said agent is Li2O-(Si, Ti)O2-MO series (where MO is at least one of Al2O3 and ZrO2). The anti-reducing dielectric ceramic composition according to claim 2, wherein said agent is SiO2-TiO2-XO series (where XO is at least one substance selected from a group consisting of BaO, SrO, CaO, MgO, ZnO and MnO). The anti-reducing dielectric ceramic composition according to claim 6, wherein said agent contains at least one substance selected from Al2O3 and ZrO2. The anti-reducing dielectric ceramic composition according to claim 2, wherein said agent is Li2O-B2O3-(Si, Ti)O2 series. The anti-reducing dielectric ceramic composition according to claim 8, wherein said agent contains at least one substance selected from Al2O3 and ZrO2. The anti-reducing dielectric ceramic composition according to claim 2, wherein said agent is B2O3-Al2O3-XO series (where XO is at least one substance selected from a group consisting of BaO, SrO, CaO, MgO, ZnO and MnO). The anti-reducing dielectric ceramic composition according to any one of claims 2 to 10, wherein the content of said agent is 20 parts by weight or lower with respect to 100 parts by weight in total of the main component and the accessory component. A monolithic ceramic capacitor including a plurality of dielectric ceramic layers, internal electrodes formed between the dielectric ceramic layers, external electrodes electrically connected with the internal electrodes, characterized in that said dielectric ceramic layers are made of a dielectric ceramic composition recited in any one of claims 1 to 11, each of said internal electrodes contains a base metal as its main component. The monolithic ceramic capacitor as claimed in claim 12, wherein said base metal is nickel or copper.
Anspruch[fr]
Composition céramique diélectrique antiréductrice, comprenant des éléments métalliques M (M: Ca, ou Ca et Sr), Zr et Ti, lorsqu'ils sont représentés par une formule (Ca1-xSrx)m(Zr1-yTiy)O3, où les valeurs de x, y et m appartiennent aux intervalles suivants :

0 ≤ x < 0,5

0,60 < y ≤ 0,85

0,85 < m < 1,30

de manière à former un composant principal, toutes les 100 moles du composant principal sont mélangées à au moins un composé parmi un composé de manganèse et un composé de magnésium incorporé en tant que composant auxiliaire dans l'intervalle allant de 0,1 à 6 moles en termes de MnO et de MgO, respectivement.
Composition céramique diélectrique antiréductrice selon la revendication 1, dans laquelle ladite composition contient en outre un agent promoteur du frittage. Composition céramique diélectrique antiréductrice selon la revendication 2, dans laquelle ledit agent contient au moins un élément parmi Si et B. Composition céramique diélectrique antiréductrice selon la revendication 2, dans laquelle ledit agent est SiO2. Composition céramique diélectrique antiréductrice selon la revendication 2, dans laquelle ledit agent est la série Li2O-(Si, Ti)O2-MO (où MO est au moins une substance parmi Al2O3 et ZrO2). Composition céramique diélectrique antiréductrice selon la revendication 2, dans laquelle ledit agent est la série SiO2-TiO2-XO (où XO est au moins une substance choisie parmi le groupe comprenant BaO, SrO, CaO, MgO, ZnO et MnO). Composition céramique diélectrique antiréductrice selon la revendication 6, dans laquelle ledit agent contient au moins une substance choisie parmi Al2O3 et ZrO2. Composition céramique diélectrique antiréductrice selon la revendication 2, dans laquelle ledit agent est la série Li2O-B2O3-(Si, Ti)O2. Composition céramique diélectrique antiréductrice selon la revendication 8, dans laquelle ledit agent contient au moins une substance choisie parmi Al2O3 et ZrO2. Composition céramique diélectrique antiréductrice selon la revendication 2, dans laquelle ledit agent est la série B2O3-Al2O3-XO (où XO est au moins une substance choisie parmi un groupe comprenant BaO, SrO, CaO, MgO, ZnO et MnO). Composition céramique diélectrique antiréductrice selon l'une quelconque des revendications 2 à 10, dans laquelle la teneur en ledit agent est inférieure ou égale à 20 parties en poids par rapport à 100 parties en poids au total du composant principal et du composant auxiliaire. Condensateur céramique monolithique comportant une pluralité de couches céramiques diélectriques, d'électrodes internes formées entre les couches céramiques diélectriques, d'électrodes externes reliées électriquement aux électrodes internes, caractérisé en ce que lesdites couches céramiques diélectriques sont constituées d'une composition céramique diélectrique selon l'une quelconque des revendications 1 à 11, chacune desdites électrodes internes contient un métal de base en tant que composant principal. Condensateur céramique monolithique selon la revendication 12, dans lequel ledit métal de base est le nickel ou le cuivre.






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