Technical Field
The present invention relates to a pile (standing hair)
fabric product that has excellent hair handling and a touch equivalent to natural
fur.
Background Art
In general, standing fibers forming natural fur include
relatively long guard hairs whose roots are thick and tips are thin and relatively
short thin ground hairs, and are excellent in recovery while providing a soft hand.
On the other hand, many pile fabric products made of synthetic fibers conventionally
have been suggested and put on the market; however, because of the longitudinally
uniform thickness of their material fibers, the use of synthetic fibers whose thickness
is equal to the thickness of the roots of the natural fur causes a considerable
degradation of the softness of the fibers, whereas the use of fibers whose thickness
is equal to the thickness of the tips thereof brings about a hand lacking stiffness.
For these reasons, it has not yet been possible to achieve a pile product having
a touch equivalent to natural fur.
In response, various technologies have been disclosed so
far. For example, (Patent document 1) shows a technology in which, by forming a
pile fabric from shrinkable fibers whose coefficient of friction between fibers
is equal to or smaller than 0.230 and non-shrinkable fibers whose cross-section
is flat or elliptical, it is possible to achieve all of soft feeling, blooming properties
and standing hair.
Also, (Patent document 2) mentions that modacrylic synthetic
fibers with a rough surface that have a constant center line roughness along an
outer periphery of its cross-section show a maximum effect of silicon treatment
and consequently achieve an extremely favorable hand like animal fur.
On the other hand, various methods such as the one using
fibers whose cross-sections have different shapes and the one splitting the fiber
tips have been suggested. For example, as shown in (Patent document 3), there is
a technology in which, utilizing a fiber whose tip splits so as to achieve a Y-shaped
cross-section, a force is applied to the cross-section of the fiber so that the
tip splits, thereby achieving a unique hand with a soft touch despite the thickness
of the root.
Further, (Patent document 4) shows that a pile product
formed of fibers that have a specific monofilament fineness and whose cross-sections
have different shapes represented by a dumbbell shape, a Y-shape and a cruciform
in which this monofilament fineness and a geometrical moment of inertia are in a
certain relationship shows a hand like natural fur.
(Patent document 5), (Patent document 6) and (Patent document
7) show technologies regarding a pile fabric having hair handling, bulkiness and
a soft touch provided by using a raw cotton for pile that has specific flatness,
fineness and the number and size of asperities on the fiber surface attributed to
these cross-sectional shapes of the fibers.
Moreover, (Patent document 8) mentions that fibers whose
cross-sections have different shapes are provided, and these fibers with controlled
cross-sectional shapes are used for guard hair portions, so that a pile fabric with
an excellent touch showing specific thickness-compressive stress characteristics
can be achieved.
However, the pile fabrics obtained as above or the pile
fabrics formed by using these raw cottons do not achieve all of soft feeling, voluminousness
and recovery in a sufficient manner.
Patent document 1:
JP 8(1996)-260289 A
Patent document 2:
JP 11(1999)-21769 A
Patent document 3:
JP 1(1989)-51564 A
Patent document 4:
JP 11(1999)-217725 A
Patent document 5:
JP 8(1996)-260234 A
Patent document 6:
JP 9(1997
)-
78375 A
Patent document 7:
JP 9(1997
)-
78378 A
Patent document 8:
JP 10(1998)-158959 A
Disclosure of Invention
Problem to be Solved by the Invention
The object of the present invention is to achieve a pile
(standing hair) fabric product that has an excellent hair handling and a touch equivalent
to natural fur.
Means for Solving Problem
The present invention relates to a pile fabric including
40 wt% to 80 wt% of a modacrylic fiber (A) having a flat cross-section whose flatness
ranges from 9 to 15, a fineness of 6 to 10 dtex and 0.25 to 1.5 µm asperities
on a fiber surface in a direction perpendicular to a fiber axis with respect to
fibers forming an overall pile portion, and 20 wt% to 60 wt% of a modacrylic fiber
(B) having a cross-section whose flatness ranges from 1 to 4 and a fineness of 2
to 8 dtex with respect to the overall pile portion. The pile fabric has an average
pile length of 12 to 30 mm.
As a preferable mode, the present invention relates to
the pile fabric according to claim 2, including 5 wt% to 25 wt% of a modacrylic
fiber (C) having a flat shape whose flatness ranges from 3 to 15 and a fineness
of 12 to 33 dtex with respect to the fibers forming the overall pile portion.
Also, at this time, it is preferable that the modacrylic
fiber (B) is a non-shrinkable modacrylic fiber. Further, the weight of acrylonitrile
in a polymer forming the modacrylic fiber (A) is not particularly limited but more
preferably is 30 wt% to 70 wt%.
It is preferable that organopolysiloxane adheres to a fiber
surface of the modacrylic fiber (B). The asperities on the fiber surface of the
modacrylic fiber (A) in the direction perpendicular to the fiber axis are formed
of a cellulose derivative, whereby the effect of the present invention becomes remarkable.
Effects of the Invention
With the pile fabric according to the present invention,
it is possible to achieve favorable hair handling provided in natural fur.
Description of the Invention
The present invention relates to a pile fabric including
40 wt% to 80 wt% of a modacrylic fiber (A) having a flat cross-section whose flatness
ranges from 9 to 15, a fineness of 6 to 10 dtex and 0.25 to 1.5 µm asperities
on a fiber surface in a direction perpendicular to a fiber axis with respect to
fibers forming an overall pile portion, and 20 wt% to 60 wt% of a modacrylic fiber
(B) having a cross-section whose flatness ranges from 1 to 4 and a fineness of 2
to 8 dtex with respect to the overall pile portion. The pile fabric has an average
pile length of 12 to 30 mm.
Herein, the flatness refers to a ratio between the length
of a major axis and that of a minor axis of the fiber cross-section and, more specifically
is expressed by a value obtained by dividing the length of the major axis by that
of the minor axis. Also, the flat cross-section is a cross-section in a shape selected
from the group consisting of an elliptical shape, a crossed circular shape, a cocoon
shape, a pear shape, a dog bone shape and a bowknot shape.
When the flatness of the modacrylic fiber (A) is smaller
than 9, fibers to be blended are bound together if they have a small fineness, so
that the hair handling as the pile fabric tends to become poor. On the other hand,
when the flatness exceeds 15, the pile fabric tends to lack the recovery due to
the relatively small fineness of the modacrylic fiber (A).
Lacking the recovery means that, even after applying a
vertical load to the pile fabric from immediately above and then removing the load,
the fibers forming the pile cannot recover their original state from the compressed
state easily.
Furthermore, when the fineness is smaller than 6 dtex,
the relatively large flatness of the modacrylic fiber (A) results in lack of voluminousness
and small resilience. On the other hand, when the fineness exceeds 10 dtex, the
pile fabric tends to have a slightly hard touch, which is not preferable.
Also, when the asperities on the fiber surface of the modacrylic
fiber (A) in the direction perpendicular to the fiber axis are less than 0.25 µm,
even the fiber configuration described in the present invention cannot provide an
excellent hair handling, for example, tackiness is generated in the pile fabric,
and achieves no significant difference from conventional products. On the other
hand, when the asperities exceed 1.5 µm, there is a tendency that the touch
becomes rough and the fibers themselves become easy to break, resulting in lower
workability such as spinning characteristics.
When the ratio of such a modacrylic fiber (A) is smaller
than 40 wt% with respect to the fibers forming the overall pile portion, the pile
fabric does not exhibit the characteristics of the modacrylic fiber (A) defined
by the cross-sectional shape of the fibers, the fineness and the surface asperities
and thus does not achieve an excellent hair handling with no difference from the
conventional products. On the other hand, the ratio equal to or larger than 80 wt%
brings about a poor sliver strength, which results in lower workability such as
that in carding, and the formed pile fabric lacks the voluminousness and resilience.
A preferable mode includes 40 wt% to 80 wt%, more preferably
50 wt% to 75 wt%, of the modacrylic fiber (A) with respect to the fibers forming
the overall pile portion, and 20 wt% to 60 wt%, more preferably 25 wt% to 50 wt%,
of the modacrylic fiber (B) having a cross-section whose flatness ranges from 1
to 4, preferably 1.5 to 3.5, and a fineness of 2 to 8 dtex, more preferably 3 to
5.7 dtex, with respect to the overall pile portion.
When the ratio of this modacrylic fiber (A) is smaller
than 40 wt% with respect to the fibers forming the overall pile portion, an excellent
hair handling is not achieved, while providing no difference from the conventional
products for the above-described reasons. On the other hand, the ratio exceeding
80 wt% shows a small effect of blending the modacrylic fiber (B) when the file fabric
is touched, and thus the pile fabric lacks the voluminousness and recovery.
Furthermore, when the flatness of the cross-section of
the modacrylic fiber (B) exceeds 4, the flatness of all the fibers forming the pile
portion is large in the case where the modacrylic fiber (B) is blended with the
modacrylic fiber (A), resulting in lack of voluminousness and small resilience.
When the fineness is smaller than 2 dtex, the large flatness
of the modacrylic fiber (A) to be blended also results in lack of voluminousness
and small resilience. On the other hand, when the fineness exceeds 8 dtex, the modacrylic
fiber (B) is blended with the modacrylic fiber (A), whereby the pile fabric tends
to have a hard touch despite the large flatness of the modacrylic fiber (A).
The blend ratio of the modacrylic fiber (B) smaller than
20 wt% with respect to the fibers forming the overall pile portion shows a small
effect of blending the modacrylic fiber (B) when the file fabric is touched, and
thus the pile fabric lacks the voluminousness and recovery. On the other hand, the
ratio exceeding 60 wt% shows a small effect of blending the modacrylic fiber (A),
and the fibers tend to be bound together and do not exhibit a favorable hair handling.
As a further preferable mode, the pile fabric includes
5 wt% to 25 wt%, preferably 10 wt% to 20 wt%, of a modacrylic fiber (C) having a
cross-section whose flatness is 3 to 15, preferably 6 to 13, and a fineness of 12
to 33 dtex, preferably 15 to 25 dtex, with respect to the fibers forming the overall
pile portion.
The purpose and effect of blending the modacrylic fiber
(C) are to provide a feeling of guard hairs of natural fur. In view of them, the
flatness smaller than 3 leads to a touch harder than the guard hairs because of
the large fineness of the modacrylic fiber (C). On the other hand, when the flatness
is equal to or larger than 15, the relatively large fineness of the modacrylic fiber
(C) leads to an incongruent appearance such that the fiber cross-section is noticeable.
Here, the above-noted feeling of guard hairs refers to the feeling of standing hairs
that can be felt in the soft touch when touching the natural fur.
Also, the fineness smaller than 12 dtex cannot exhibit
the feeling of guard hairs, which is an expected effect, whereas the fineness equal
to or larger than 33 dtex brings about a hard touch due to the large fineness of
the monofilament.
At this time, when the ratio of the modacrylic fiber (C)
is smaller than 5 wt% with respect to the fibers forming the overall pile portion,
the effect of blending the modacrylic fiber (C) is not sufficient. On the other
hand, the ratio equal to or larger than 25 wt% is not preferable because the large
fineness of the modacrylic fiber results in a touch far from the feeling of guard
hairs, that is, a touch such that fingers get snagged as if foreign matters are
present.
Also, as a preferable mode of the pile fabric according
to the present invention, the range of average pile length has a lower limit of
a pile value of 12 mm, preferably 13 mm and more preferably 15 mm and an upper limit
thereof of 30 mm, preferably 28 mm and more preferably 25 mm. Regarding the lower
limit of the average pile length, the pile length smaller than 12 mm is not preferable
because the touch becomes hard. The pile length of 12 mm does not impair considerably
the characteristic of the present invention of achieving both of the soft feeling
and the voluminousness, though the touch becomes slightly hard. The pile length
of 13 mm is the lower limit at which both of the soft feeling and the voluminousness
can be achieved. Further, the pile length of 15 mm achieves the pile fabric that
achieves both of the most appropriate soft feeling and the voluminousness. On the
other hand, regarding the upper limit of the pile length, the pile length larger
than 30 mm is not preferable because the resilience is poor. The pile length of
30 mm corresponds to a resilience limit, though an extremely soft touch is provided.
The pile length of 28 mm achieves a favorable resilience, and that of 25 mm achieves
the most appropriate resilience and soft feeling. Therefore, the most favorable
mode of the pile fabric has a pile length ranging from 15 to 25 mm.
Also, it is preferable that the modacrylic fiber (B) is
a non-shrinkable modacrylic fiber. If the modacrylic fiber (B) is a shrinkable fiber,
shrinkage of this shrinkable fiber due to tentering in the pile manufacturing process
involves the modacrylic fiber (A), so that the hair handling at the root of the
pile portion tends to be impaired considerably.
At this time, the non-shrinkable fiber refers to a fiber
whose dry heat shrinkage is smaller than 5%. The dry heat shrinkage is calculated
by the equation below, where Lb is a sample length of an unshrunken fiber measured
first under a load of 8.83 × 10-3 cN/dtex and La is a sample length
of a shrunken fiber obtained by treating the unshrunken fiber sample subsequently
under no load in a burning oven at 130°C for 20 minutes.
Further, the weight of acrylonitrile in the polymer forming the modacrylic fiber
(A) in the present invention is not particularly limited but more preferably is
30 wt% to 70 wt%, and at this time, the polymer contains 65 wt% to 2 wt% of other
vinyl-based monomers that are copolymerizable with acrylonitrile and 0 wt% to 10
wt% of vinyl-based monomers containing a sulfonic group that are copolymerizable
with them. The above-noted vinyl-based monomers that are copolymerizable with acrylonitrile
may be known vinyl compounds such as vinyl halides and vinylidene halides represented
by vinyl chloride, vinylidene chloride, vinyl bromide, vinylidene bromide, etc.,
unsaturated carboxylic acids represented by an acrylic acid and a methacrylic acid
and salts thereof, acrylic esters and methacrylic esters represented by methyl acrylate
and methyl methacrylate, unsaturated carboxylic esters represented by glycidyl methacrylate,
etc., vinyl esters represented by vinyl acetate and vinyl butyrate, vinyl-based
amides represented by acrylamide and methacrylamide, methallylsulfonic acids, vinylpyridines,
methyl vinyl ethers and methacrylonitrile, and may be acrylic copolymers obtained
by copolymerizing one kind or two or more kinds thereof.
Also, the above-noted vinyl-based monomers containing a
sulfonic group can be a styrenesulfonic acid, a parastyrenesulfonic acid, an allylsulfonic
acid, a methallylsulfonic acid, a paramethacryloyl oxybenzenesulfonic acid, and
a methacryloyl oxypropylsulfonic acid, or metal salts thereof and amine salts thereof.
Moreover, organopolysiloxane is made to adhere to the surface
of the modacrylic fiber (B) forming the pile fabric according to the present invention,
whereby the effect of the present invention becomes remarkable. In this case, it
does not matter whether or not the organosiloxane is made to adhere to the modacrylic
fiber (A).
The above-noted organosiloxane preferably is at least one
selected from the group consisting of dimethylpolysiloxane, amino modified silicone,
epoxy modified silicone and carboxy modified silicone. The above-noted organopolysiloxane
is made to adhere to the fiber surface in the form of a treatment solution. A further
softening effect can be produced by treating the fiber at 90°C or higher after
the adhesion of the treatment solution, and this treatment is carried out more preferably
at 100°C or higher. Also, the treatment solution mainly containing the above-noted
organopolysiloxane preferably is a solution prepared by emulsifying organopolysiloxane
in water using a surfactant for its viscosity adjustment and stability over time.
Furthermore, this emulsified treatment solution preferably has a viscosity of equal
to or smaller than 500 cp (at room temperature) in order to increase an affinity
for the fibers. The amount of the organopolysiloxane adhering to the fiber surface
is 0.01 wt% to 0.7 wt%, preferably 0.03 wt% to 0.5 wt%, with respect to a fiber
weight. The amount smaller than 0.01 wt% achieves small sliminess and cannot provide
a hand like natural fur, whereas that larger than 0.7 wt% generates stickiness and
may impair a hand.
The asperities on the fiber surface of the modacrylic fiber
(B) forming the pile fabric according to the present invention in a direction of
the fiber axis are formed of a cellulose derivative, whereby the effect of the present
invention becomes remarkable. The above-noted cellulose derivative more preferably
is a cellulose ester such as cellulose acetate, cellulose propionate, cellulose
butyrate, etc.
Examples
The following is a more specific description of the present
invention by way of examples. However, it should be noted that the present invention
is by no means limited to these examples. Before the description of the examples,
an analysis measurement condition and an evaluation method will be described.
(1) Measurement of fineness
The fineness was measured using an auto-vibronic fineness
measuring instrument Denior Computer DC-11 (manufactured by Search Co., Ltd.), and
an average of the samples (the number of samples n = 25) was used.
(2) Measurement of flatness
Using S-3500N scanning electron microscope (manufactured
by Hitachi, Ltd.), a cross-section of a fiber on which Au was deposited by Ion Coater
IB-3 (manufactured by EIKO Engineering Co., Ltd.) was observed, thus measuring a
major axis length and a minor axis length of the fiber cross-section. For the major
axis length and the minor axis length, an average of the samples (n = 25) was used.
From the major axis length and the minor axis length, Flatness = Major axis length
/ Minor axis length was calculated.
(3) Measurement of height difference on fiber surface
A single fiber was fixed onto a slide glass with a double-sided
sticky tape at no tension, and measurement was conducted at 10 points along directions
perpendicular to a fiber axis using a laser microscope manufactured by KEYENCE CORPORATION.
The asperities were measured as follows: the shape of the fiber surface was expressed
as a waveform with a vertical axis showing the height of the asperities and a horizontal
axis showing the length along a direction of an outer periphery of the fiber, and
a difference between an average of five maximum heights and an average of five minimum
heights was considered as the height difference. At this time, a measurement range
at each point was 10 µm, and the average of the values at 10 points was indicated
as the height difference. Also, these values were subjected to an automatic inclination
correction with a cutoff value being set to 0.08 mm. The measurement condition of
a probe microscope was a 150X objective lens, a 20X built-in lens and a scan pitch
of 0.05 µm.
(4) Production of high pile fabric
The resultant fibers were subjected to necessary treatments
and operations such as providing an oil solution, providing mechanical crimps and
cutting, etc. At this time, the mechanical crimps refer to crimps obtained by a
known method such as a gear crimp method or a stuffing box method, without any particular
limitation. The crimp shape was preferable if the percentage of crimp was 4% to
15%, preferably 5% to 10%, and it was appropriate that the number of crests of the
crimps range from 6 to 15 per inch and preferably from 8 to 13 per inch. The above-noted
percentage of crimp was obtained by a measurement method represented by JIS-L1074.
Thereafter, these fibers were cut, and a pile fabric was woven using a sliver loom.
Then, a pre-polishing treatment and a pre-shirring treatment were conducted at 120°C
so as to align the pile lengths, and then a back surface of the pile was coated
with an acrylic ester-based adhesive. Subsequently, the pile was polished at 155°C
and then brushed, followed by a combination of polishing and shirring at 135°C,
120°C and 90°C (twice for each process), thereby removing the crimps in
a surface layer portion of standing hairs. In this manner, a pile fabric having
a certain pile length was produced.
(5) Evaluation of touch of pile fabric
The touch of the pile fabric produced as above was evaluated
by a sensory test on a scale of A to D as follows in terms of hair handling.
A: having an excellent hair handling and providing a touch
extremely similar to natural fur
B: having a favorable hair handling and providing a touch
similar to natural fur
C: having a slightly poor hair handling compared with natural
fur
D: having an insufficient hair handling and being far from
natural fur
(6) Measurement of average pile length
The fibers forming the pile portion in the pile fabric
were made to stand vertically such that the piles were aligned. Then, the length
from a root to a tip of a long pile portion or a short pile portion of the fibers
forming the pile portion (not the length from the back surface of the pile fabric)
was measured using vernier calipers at 10 points, and an average of them was determined
as the average pile length.
(Manufacturing Examples 1 to 5)
An acrylic copolymer containing 49 parts by weight of acrylonitrile,
50 parts by weight of vinyl chloride and 1 part by weight of sodium styrenesulfonate
was dissolved in acetone. Further, a spinning solution prepared by adding 2.3 parts
by weight of highly dispersive titanium oxide having a particle size distribution
of equal to or smaller than 0.8 µm (A-160; manufactured by Sakai Chemical Industry
Co., Ltd.) and 2.5 parts by weight of cellulose acetate to 100 parts by weight of
the acrylic copolymer was extruded through a spinneret whose hole diameter was 0.04
x 0.65 mm and whose number of holes was 7133 so as to carry out wet spinning into
a coagulation bath containing an aqueous solution with an acetone concentration
of 30% and then through two baths respectively containing aqueous solutions with
an acetone concentration of 35% and 25%, followed by drawing by 2.0 times. Thereafter,
in water-washing bath at 75°C, primary drawing to draw the fibers to 3.0 times
their original length in combination with the above-mentioned drawing was carried
out. Subsequently, after provided with the oil solution, the resultant fibers were
dried in an atmosphere at 125°C, followed by further drawing at 125°C
so as to obtain a final draft with a length 6.5 times its original length. Then,
a mild heat treatment was carried out in a dry heat atmosphere at 145°C, thus
obtaining 7.8 dtex fibers (Manufacturing Example 1), 5.6 dtex fibers (Manufacturing
Example 2), 6.5 dtex fibers (Manufacturing Example 3), 9.5 dtex fibers (Manufacturing
Example 4) or 11 dtex fibers (Manufacturing Example 5). At this time, all of them
had a flatness of 12.
(Manufacturing Example 6)
A spinning solution similar to that in Manufacturing Example
1 was used and extruded through a spinneret whose hole diameter was 0.05 x 0.43
mm and whose number of holes was 8333 under a spinning condition similar to that
in Manufacturing Example 1, thus obtaining 7.8 dtex fibers having a flatness of
7.6.
(Manufacturing Example 7)
Under a condition similar to that in Manufacturing Example
1 except that titanium oxide and cellulose acetate were not added as the additives,
7.8 dtex fibers having a flatness of 12 was manufactured.
(Manufacturing Example 8)
An acrylic copolymer containing 93 parts by weight of acrylonitrile
and 7 parts by weight of vinyl acetate was dissolved in dimethylacetamide (DMAc).
Further, a spinning solution prepared by adding 2.0 parts by weight of highly dispersive
titanium oxide having a particle size distribution of equal to or smaller than 0.8
µm (A-160; manufactured by Sakai Chemical Industry Co., Ltd.) to 100 parts
by weight of the acrylic copolymer was extruded through a spinneret whose hole diameter
was 0.04 x 0.65 mm and whose number of holes was 7133 so as to carry out wet spinning
into a coagulation bath containing an aqueous solution with a DMAc concentration
of 60%, followed by drawing by 1.6 times. Subsequently, these coagulated fibers
were drawn by 5.0 times while washing the solvent off from the fibers in boiling
water, followed by drying by heat rollers at 130°C. Thereafter, a mild heat
treatment was carried out in a pressurized steam atmosphere at 2.5 Kg/cm2G,
thus obtaining 7.8 dtex fibers. At this time, the fibers had a flatness of 13.
Table 1 shows the compositions and characteristics of the
fibers obtained in Manufacturing Examples 1 to 8.
[Table 1]
Table 1
Polymer composition
wt% of AN
Solvent
Fineness (dtex)
Flatness
Height difference on fiber surface (µm)
Manufacturing Ex. 1
AN/VCL
49
Acetone
7.8
12
0.73
Manufacturing Ex. 2
AN/VCL
49
Acetone
5.6
12
0.62
Manufacturing Ex. 3
AN/VCL
49
Acetone
6.5
12
0.69
Manufacturing Ex. 4
AN/VCL
49
Acetone
9.5
12
0.69
Manufacturing Ex. 5
AN/VCL
49
Acetone
11
12
0.81
Manufacturing Ex. 6
AN/VCL
49
Acetone
7.8
7.6
0.69
Manufacturing Ex. 7
AN/VCL
49
Acetone
7.8
12
0.19
Manufacturing Ex. 8
AN/VAc
93
DMAc
7.8
13
0.51
Note: in Polymer composition
in the table above, AN indicates acrylonitrile, VCL indicates vinyl chloride, VAc
indicates vinyl acetate, and DMAc indicates dimethylacetamide.
In fibers used in Examples and Comparative Examples below,
"Kanekalon (registered trademark)" RCL and Fankle H 105 are modacrylic non-shrinkable
fibers, "Kanekalon (registered trademark)" AH is a fiber obtained by making organopolysiloxane
adhere to a modacrylic non-shrinkable fiber, and "Kanekalon (registered trademark)"
AHD is a fiber obtained by making organopolysiloxane adhere to a modacrylic shrinkable
fiber.
(Examples 1 and 2)
After provided with the crimps, the fibers obtained in
Manufacturing Example 1 were cut to 38 mm. Next, these fibers were packed in an
Obermeyer dyeing machine at a packing density of 0.30 g/cm3, thus performing
dyeing. A dyeing formula at this time was a blend of dyes of 0.0228 %omf Maxilon
Yellow 2RL 200%, 0.0075 %omf Maxilon Red GRL 150% and 0.0063 %omf Maxilon Blue GRL
300% (all manufactured by Ciba Specialty Chemicals.) and dyeing assistants of 0.5
%omf Levenol WX (manufactured by Kao Corporation) and 0.5 g/L Ultra MT #100 (manufactured
by Mitejima Chemical Co., Ltd.), and the fibers were heated from room temperature
at 3°C/min. and, when reached at 98°C, dyed while kept at that temperature
for 60 minutes. On the other hand, commercially available modacrylic fibers "Kanekalon
(registered trademark)" AH (manufactured by KANEKA CORPORATION) were dyed under
the same condition as above. These fibers were blended at the ratios of 70 wt% to
30 wt% (Example 1) and 50 wt% to 50 wt% (Example 2) so as to produce pile fabrics.
At this time, both of these pile fabrics had a final density of 650 g/m2.
The pile in Example 1 was cut to have an average pile length of 18 mm, and that
in Example 2 was cut to have an average pile length of 22 mm. The resultant pile
fabrics both had an excellent hair handling and a touch extremely similar to animal
fur as shown in Table 2.
[Table 2]
Incidentally, "Kanekalon (registered trademark)" AH used
in Example 1 having a fineness of 3.3 dtex and a length of 38 mm had a fiber cross-section
whose flatness was 3, and "Kanekalon (registered trademark)" AH used in Example
2 having a fineness of 5.6 dtex and a length of 38 mm had a fiber cross-section
whose flatness was 3.
(Examples 3 and 4)
The fibers obtained in Manufacturing Examples 3 and 4 were
provided with the crimps, cut and dyed similarly to Example 1. Furthermore, these
fibers were blended with modacrylic fibers "Kanekalon (registered trademark)" AH
having a fineness of 3.3 dtex and a length of 38 mm (manufactured by KANEKA CORPORATION)
dyed under the same condition as above at the ratio of 50 wt% to 50 wt% so as to
produce pile fabrics. At this time, the resultant pile fabrics had a final density
of 650 g/m2, and the piles were cut to have an average pile length of
18 mm. The resultant pile fabrics all had a favorable hair handling and a touch
similar to natural fur as shown in Table 2. Similarly, the "Kanekalon (registered
trademark)" AH having a fineness of 3.3 dtex and a length of 38 mm had a fiber cross-section
whose flatness was 3.
(Example 5)
The fibers obtained in Manufacturing Example 1 were provided
with the crimps, cut and dyed similarly to Example 1. Furthermore, these fibers
were blended with modacrylic fibers "Kanekalon (registered trademark)" AH having
a fineness of 3.3 dtex and a length of 38 mm (manufactured by KANEKA CORPORATION)
and modacrylic fibers "Kanekalon (registered trademark)" RCL having a fineness of
17 dtex and a length of 51 mm (manufactured by KANEKA CORPORATION) dyed under the
same condition as above at the ratio of 60 wt% : 25 wt% : 15 wt% in this order so
as to produce a pile fabric. At this time, the resultant pile fabric had a final
density of 650 g/m2, and the pile was cut to have an average pile length
of 18 mm. The resultant pile fabric had an excellent hair handling and a touch extremely
similar to animal fur as shown in Table 2. Incidentally, the "Kanekalon (registered
trademark)" AH having a fineness of 3.3 dtex and a length of 38 mm had a fiber cross-section
whose flatness was 3, and the "Kanekalon (registered trademark)" RCL having a fineness
of 17 dtex and a length of 51 mm had a fiber cross-section whose flatness was 7.5.
(Example 6)
The fibers obtained in Manufacturing Example 1 were provided
with the crimps, cut and dyed similarly to Example 1. Furthermore, these fibers
were blended with modacrylic fibers "Kanekalon (registered trademark)" AHD(10) having
a fineness of 4.4 dtex and a length of 32 mm (manufactured by KANEKA CORPORATION)
at the ratio of 50 wt% to 50 wt% so as to produce a pile fabric. At this time, the
resultant pile fabric had a final density of 550 g/m2, and the pile was cut to have
an average pile length of 15 mm. The resultant pile fabric had a favorable hair
handling and a touch similar to natural fur as shown in Table 2. Incidentally, the
"Kanekalon (registered trademark)" AHD having a fineness of 4.4 dtex and a length
of 32 mm had a fiber cross-section whose flatness was 3 and a shrinkage of 32%.
(Example 7)
The fibers obtained in Manufacturing Example 8 were provided
with the crimps, cut and dyed similarly to Example 1. Furthermore, these fibers
were blended with modacrylic fibers "Kanekalon (registered trademark)" AH having
a fineness of 3.3 dtex and a length of 38 mm (manufactured by KANEKA CORPORATION)
dyed under the same condition as above at the ratio of 50 wt% to 50 wt% so as to
produce a pile fabric. At this time, the resultant pile fabric had a final density
of 650 g/m2, and the pile was cut to have an average pile length of 18
mm. The resultant pile fabric had a favorable hair handling and a touch similar
to natural fur as shown in Table 2. Similarly, the "Kanekalon (registered trademark)"
AH having a fineness of 3.3 dtex and a length of 38 mm had a fiber cross-section
whose flatness was 3.
(Comparative Example 1)
The fibers obtained in Manufacturing Example 1 were provided
with the crimps, cut and dyed similarly to Example 1. Furthermore, these fibers
were blended with modacrylic fibers "Kanekalon (registered trademark)" AH having
a fineness of 3.3 dtex and a length of 38 mm (manufactured by KANEKA CORPORATION)
dyed under the same condition as above at the ratio of 70 wt% to 30 wt% so as to
produce a pile fabric. At this time, the resultant pile fabric all had a final density
of 650 g/m2, and the pile was cut to have an average pile length of 35
mm. The resultant pile fabric had an insufficient hair handling and was far from
natural fur as shown in Table 2. Similarly, the "Kanekalon (registered trademark)"
AH having a fineness of 3.3 dtex and a length of 38 mm had a fiber cross-section
whose flatness was 3.
(Comparative Examples 2 to 5)
The fibers obtained in Manufacturing Examples 2 and 5 to
7 were provided with the crimps, cut and dyed similarly to Example 1. Furthermore,
these fibers were blended with modacrylic fibers "Kanekalon (registered trademark)"
AH having a fineness of 3.3 dtex and a length of 38 mm (manufactured by KANEKA CORPORATION)
dyed under the same condition as above at the ratio of 70 wt% to 30 wt% so as to
produce pile fabrics. At this time, the resultant pile fabrics all had a final density
of 650 g/m2, and the piles were cut to have an average pile length of
18 mm. The resultant pile fabrics had a slightly poor hair handling compared with
natural fur or an insufficient hair handling and were far from natural fur as shown
in Table 2. Similarly, the "Kanekalon (registered trademark)" AH having a fineness
of 3.3 dtex and a length of 38 mm had a fiber cross-section whose flatness was 3.
(Comparative Example 6)
The fibers obtained in Manufacturing Example 1 were provided
with the crimps, cut and dyed similarly to Example 1. Furthermore, these fibers
were blended with modacrylic fibers "Kanekalon (registered trademark)" AH having
a fineness of 3.3 dtex and a length of 38 mm (manufactured by KANEKA CORPORATION)
dyed under the same condition as above at the ratio of 30 wt% to 70 wt% so as to
produce a pile fabric. At this time, the resultant pile fabric had a final density
of 650 g/m2, and the pile was cut to have an average pile length of 18
mm. The resultant pile fabric had a slightly poor hair handling compared with natural
fur as shown in Table 2. Similarly, the "Kanekalon (registered trademark)" AH having
a fineness of 3.3 dtex and a length of 38 mm had a fiber cross-section whose flatness
was 3.
(Comparative Examples 7 and 8)
The fibers obtained in Manufacturing Example 1 were provided
with the crimps, cut and dyed similarly to Example 1. Furthermore, these fibers
were blended with modacrylic fibers "Kanekalon (registered trademark)" RCL having
a fineness of 7.8 dtex and a length of 38 mm (manufactured by KANEKA CORPORATION)
dyed under the same condition as above at the ratio of 70 wt% to 30 wt% (Comparative
Example 7) and with acrylic fibers "Fankle (registered trademark)" H105 having a
fineness of 5.6 dtex and a length of 38 mm (manufactured by MITSUBISHI RAYON CO.,
LTD.) dyed under the same condition as above at the ratio of 70 wt% to 30 wt% (Comparative
Example 8) so as to produce pile fabrics. At this time, the resultant pile fabrics
had a final density of 650 g/m2, and the piles were cut to have an average
pile length of 20 mm. The resultant pile fabrics had an insufficient hair handling
and were far from natural fur as shown in Table 2. Incidentally, the "Kanekalon
(registered trademark)" RCL having a fineness of 7.8 dtex and a length of 38 mm
had a flatness of 6.0, and the "Fankle (registered trademark)" H105 having a fineness
of 5.6 dtex and a length of 38 mm had a flatness of 10.5.
Industrial Applicability
The pile fabric according to the present invention makes
it possible to achieve a favorable hair handling provided in natural fur and is
useful for a pile fabric product or the like that has a touch equivalent to natural
fur.