Technical Field
The present invention relates to an abrading plate and
a method for polishing an object such as semiconductor wafer using the abrading
plate to obtain a flat and mirror finish as known for example from document
JP-A-56 052 183
.
Background Art
Recently, as the density of circuit integration in semiconductor
devices becomes ever higher, circuit patterns are becoming finer and interline spacing
narrower. Especially, since the line width becomes finer, the depth of focus of
the stepper becomes very shallow in photolithographic reproduction of circuit patterns,
and the surface of the wafer placed at the focal plane of the stepper must be flat
to produce the required degree of image sharpness. A method of obtaining a flat
surface is to polish the object in a polishing apparatus.
A type of conventional polishing apparatus comprises a
turntable having a polishing cloth and a top ring which is pressed against the turntable
with a given pressure while the polishing object is held therebetween, and supplying
a polishing solution to the interface to produce a flat and mirror polished surface.
This approach is called chemical mechanical polishing (CMP).
Figure 1 shows essential parts of an example of a conventional
CMP apparatus. The apparatus is provided with a rotating turntable 5 having a polishing
cloth 6 such as a urethane cloth; a top ring 1 holding an object 4 such as a semiconductor
wafer 4 against the cloth 6; and a spray nozzle 9 for supplying a polishing solution
Q to the polishing cloth 6. The top ring 1 is connected to a top ring shaft 8, and
the top ring 1 holds a semiconductor wafer 4 in contact with an elastic mat 2 such
as polyurethane. The top ring 1 has a cylindrical guide ring 3 on its outer periphery
so that the wafer 4 would not be disengaged from the bottom of the top ring 1. The
guide ring 3 is fixed to the top ring 1, and the wafer 4 is held within the holding
surface so that the wafer 4 would not jump outside of the top ring due to frictional
forces with the cloth 6. The top ring 1 is supported on a spherical bearing 7 so
that it can be tilted with respect to the shaft 8.
While holding the wafer 4 in the bottom surface of the
elastic mat 2 of the top ring 1, wafer 4 is pressed against the cloth 6 on the turntable
5, and the turntable 5 and the top ring 1 are independently rotated so as to slide
the surface of the wafer 4 relative to the cloth 6 to polish the wafer 4. In this
case, a polishing solution Q is supplied from the nozzle 9 to the top surface of
the cloth 6. The polishing solution comprises abrasive particles, for example, such
as silica particles, suspended in an alkaline solution, which have two effects of
CMP for semiconductor wafer, chemical polishing using an alkaline solution, for
example, and mechanical polishing using abrasive particles.
However, the conventional polishing methods of CMP using
such a slurry solution containing numerous abrasive particles presents two operational
problems.
The first problem is that, during the initial stage of
polishing, raised regions of the surface structure is preferentially removed, but
gradually, depressed regions are also removed. Therefore, irregularities of the
surface is difficult to be decreased. It is considered that this phenomenon in CMP
is created because a relatively soft cloth is used along with freed abrasive particles
contained in the polishing solution, so that not only the raised portions but also
the depressed portion of the surface structure are also removed by such abrasive
particles. Figure 2 illustrates such problems of the conventional CMP, which shows
irregularities caused by a raised portion and depressed portion of surface film
thickness structure on the vertical axis and relative time on the horizontal axis.
As indicated in this graph, at a relative time of 1 to reach a stage of surface
removal, the raised regions are polished from a height of about 27,000 angstroms
to a height of 16,000 angstroms, but the depressed regions are also polished from
20,000 angstroms to 16,000 angstroms, at which point, the irregularities are eliminated.
Figure 3A shows surfaces profiles of a fine surface structure in an initial stage,
Figure 3B in a middle stage, and Figure 3C in a final stage of polishing. As illustrated
in these drawings, the irregularities are very difficult to be removed, and consequently,
it is a time-consuming operation.
The second problem relates to cost and environmental considerations.
The polishing solution is usually a slurry containing a fine silica powder in suspension,
but to obtain a uniformly flat surface of high quality, it is necessary to supply
the solution in a liberal quantity to the polishing surface. However, most of the
solution supplied is actually discharged as a waste solution without contributing
much to the polishing process. Polishing solutions used for high precision polishing
of semiconductor devices are expensive, which is a factor leading to a problem of
high polishing cost. Also, because such polishing solution in a slurry condition
contains a large quantity of abrasive particles such as silica particles, the maintenance
of working environment is apt to be difficult. That is, contamination of solution
supply system and drainage system by the slurry is serious, and the waste solution
must also be treated extensively before discarding. Also, after a CMP process, the
wafers are washed to remove the polishing solution, but the waste water from this
operation also must be treated in a similar manner and poses an environmental problem.
Disclosure of Invention
To solve the above described problems, it is therefore
an object of the present invention to provide an abrading plate according to claim
1 and a method according to claim 4using the abrading plate for preferentially removing
only the raised regions in a patterned semiconductor wafer having fine irregularities
fabricated on the surface, and, when the irregularities are eliminated, the abrading
plate has a self-stopping function to stop proceeding of the polishing automatically.
Another object of the present invention is to provide a
polishing method and an apparatus using the abrading plate, which easily enables
to polish additionally to remove a certain film thickness uniformly after height
difference is eliminated by polishing.
To achieve the object of the present invention, there is
provided an abrading plate which comprises the features of claim 1.
According to the present invention, the abrading plate
thus produced has an optimized composition of particles, binder and porosity by
volume, so that raised regions of the polishing surface is preferentially removed
from the object surface and depressed regions are not removed. Therefore, after
the raised regions are flattened and the surface has become level, continued polishing
will not proceed to change the film thickness of the surface structure. Stopping
or removal rate reduction is achieved automatically, and is termed a self-stopping
capability. If the abrasive particles are in excess or the binder material is insufficient,
abrasive particles are easily self-generated (released), so that abrading continues
even after a level surface has been produced, and the self-stopping function cannot
operate. If the amount of abrasive particles is insufficient or, binder material
is in excess, abrasive particles are difficult to be self-generated (released) and
polishing rate is reduced so that polishing capacity is decreased. Similar tendency
is applied to porosity, and it is preferred to have 10~40 % by volume or more preferably
15~30 % by volume to give the self-stopping capability to the abrading plate. In
other words, too much porosity makes the abrading plate too soft and promotes generation
of released particles while too little porosity makes the abrading plate too hard
to discourage self-generation of freed particles (released). Because the particles
are less than 2 µm in size, chances of scratching the wafer are reduced, but
it is preferable to use particles size of less than 0.5 µm.
In general, polishing rate is increased by having a large
number of released abrasive particles in the sliding interface. When there are lesser
number of freed abrasive particles, polishing rate is reduced, and wafer processing
ability, namely throughput is reduced. Accordingly, when the surface of the semiconductor
device patterned wafer having raised and depressed regions is polished by the abrading
plate, a high surface pressure is applied to the raised region of the wafer by the
abrading surface of the abrading plate, thus the raised portion bite and shave the
abrading surface of the abrading plate to release the abrasive particles through
initial stage to final stage of the polishing. A large number of abrasive particles
are released and produced during the polishing stage, thus polishing proceeds at
relatively large polishing rate by released abrasive particles. Therefore, in the
final stage of polishing when the surface has become level, the wafer has little
raised regions left on the wafer to bite into the abrading plate so that lesser
number of released particles are produced from the abrading plate. In the polishing,
sliding interface shifts its location constantly, the residual released abrasive
particles are lost from the sliding interface. Thus, the amount of the released
abrasive particles remaining on the sliding interface becomes extremely small, and
polishing action stops eventually thereby to provide a self-stopping function occurring
as a extreme decrease of polishing rate.
In the abrading plate, proportions of abrasive particles,
a binder material and porosity should be 10~60 % (preferably 20~50 %), 30~60 % (preferably
35~55 %), and 10~40 % (preferably 15~30 %) by volume, respectively, to achieve a
self-stopping capability as described above.
The abrading plate comprises abrasive particles having
a chemical purity of not less than 90 % (preferably higher than 94 %); and the abrading
plate comprises such particles, a binder material and porosity. Accordingly, the
abrading plate made by such abrasive particles that can be obtained easily will
present little danger of contaminating device wafers (patterned wafers).
A method according to claim 4 is presented for polishing
a semiconductor device wafer, having fine surface structure fabricated on a polishing
surface, using the abrading plate according to claim 1. The method includes in preferred
embodiments the conditioning steps of: dressing an abrading surface of the abrading
plate so as to produce a roughened structure on the abrading surface; removing released
particles attaching to said roughened structure; and polishing the polishing surface
with a conditioned abrading plate having a stabilized polishing rate generated by
the foregoing steps. According to the method, the characteristic feature of the
self-stopping function of the present abrading plate can be fully effective to be
utilized in polishing the semiconductor device wafer.
Also, the present method of polishing of semiconductor
device wafer having fine structures fabricated on the surface includes a feature
that an abrading surface of an abrading plate is dressed to produce micro-rough
surface, and released abrasive particles attached to the abrading surface are removed
before pressing onto a surface of an object to be polished, so that the abrading
surface has reached a stabilized condition to polish a blanket wafer (a wafer covered
by an overall film) at a sufficiently low polishing rate. This procedure is effective
in generating the self-stopping capability.
Also, the present method of polishing of semiconductor
device wafer having fine structures fabricated on the surface includes a feature
that the additional surface removal is performed with an abrading plate using a
liquid not containing any abrasive particles for a specific duration, followed by
additional polishing using a slurry containing abrasive particles to the surface
to be polished. A specific duration is a duration sufficient for the surface to
be leveled by removing the high and low spots. According to this method, it enables
to use the same abrading plate to obtain additional surface removal by using a slurry
containing a large amount of released abrasive particles. Because this polishing
is carried out using a slurry containing a large amount of abrasive particles, surface
removal can be achieved in a relatively short time to obtain a desired film thickness.
Also, the present method of polishing of semiconductor
device wafer having fine structures fabricated on the surface includes a feature
that the additional surface removal is performed using an abrading plate and a liquid
not containing any abrasive particles for a specific duration, followed by additional
polishing using released abrasive particles being produced from concurrent dressing
of the abrading plate. This method enables to use the same abrading plate so that
the released abrasive particles, being produced by carrying out dressing concurrently
with the polishing by abrading plate, are used to obtain quick removal of the surface
material, thereby raising the polishing rate. Therefore, it is not necessary to
have additional facility such as the polishing solution supply device so that a
regular facility based on the abrading plate can be used to perform additional surface
removal.
Also, the present method of polishing of semiconductor
device wafer having fine structures fabricated on the surface includes a feature
that additional removal is performed using an abrading plate and a liquid not containing
any abrasive particles for a specific duration, followed by additional polishing
using a polishing cloth and a slurry containing abrasive particles. This method
enables to use the existing facility to carry out additional surface removal based
on conventional slurry and polishing cloth.
Brief Description of Drawings
- Figure 1 is a schematic cross sectional view of a conventional polishing apparatus.
- Figure 2 is a graph of polishing characteristics of the apparatus shown in Figure
1.
- Figures 3A~3C are illustrations of the surface steps produced by the apparatus
having the polishing characteristics shown in Figure 2.
- Figures 4A, 4B are schematic diagrams of the essential parts of an embodiment
of the turntable type polishing apparatus of present invention, and shows a plan
view in Figure 4A and a cross sectional view in Figure 4B.
- Figure 5 is a cross sectional view of a scroll type polishing apparatus of present
invention.
- Figures 6A, 6B are schematic diagrams of the essential parts of an embodiment
of the scroll type polishing apparatus shown in Figure 5, respectively, and Figure
6A shows a plan view of a scroll mechanism and 6B shows a cross sectional view along
a plane A-A in Figure 6A.
- Figure 7A is a schematic illustration of abrading plate, abrasive particles
and polishing surface, and Figure 7B is an illustration of the relationship of the
polishing pad, abrasive particles and a polishing surface of a substrate.
- Figures 8A, 8B are illustrations to show the effects of particle size on the
stress distribution, and Figure 8A shows a case of large sized particles and Figure
8B shows a case of small sized particles.
- Figure 9 is a tri-axial graph of abrading plate parameters involving abrasive
particles, binder and porosity (volume ratio) to indicate a region B of parameters
for optimum performance for self-stopping.
- Figure 10 is a graph to show the polishing characteristics of an abrading plate
having self-stopping capability.
- Figures 11A~11C are illustrations of progressive changes of irregularities during
polishing according to the polishing characteristics of abrading plate shown in
Figure 10.
- Figure 12 is a graph to show the polishing characteristics of an abrading plate
having no self-stopping capability.
- Figures 13A~13C are illustrations to show surface elevations obtained by the
abrading plate shown in Figure 12.
- Figure 14 is a graph to show changes in the polishing rate of the abrading plate
after dressing (roughening) of the abrading plate surface.
- Figures 15A, 15B are schematic illustrations of the dressed abrading surface,
and Figure 15A shows a case of a large number of residual particles, and Figure
15B shows a case of a negligible number of residual particles.
- Figures 16A~16C are comparisons of various abrading plates: Figure 16A is with
self-stopping; Figures 16B, 16C are without self-stopping. The graphs on the left
column show transitions in polishing rate, with polishing time on x-axis and polishing
rate on y-axes; the graphs in the middle show transitions in film thickness, with
polishing time on x-axis and film thickness on y-axis; and the graphs on the right
column show comparison of initial (D1) and last (D2) stages of polishing of a blanket
wafer (BL) and a device wafer.
- Figures 17A~17D are illustrations of the steps for removing residual particles:
Figure 17A shows a brush method; Figure 17B shows a roll brush method; Figure 17C
shows a water jet method; and Figure 17D shows an ultrasonic method.
- Figures 18A, 18B are diagrams to illustrate the method of polishing in the first
embodiment of present invention.
- Figure 19 is an illustration of the changes in film thickness during the first
stage polishing and the second stage polishing.
- Figures 20A, 20B are illustrations of a method of controlling the film thickness,
and Figure 20A shows time based control and Figure 20B shows thickness based control.
- Figure 21 is a schematic diagram of a switching mechanism for changing from
a liquid W containing no abrasive particles to a slurry Q containing abrasive particles.
- Figure 22 is a flowchart of the switching process for changing from a liquid
W to a slurry Q.
- Figure 23 illustrates a method of polishing in a second embodiment.
- Figure 24 is a schematic diagram of a switching mechanism for dressing operations.
- Figure 25 is a flowchart of the switching process for the dressing operations.
- Figures 26A, 26B are illustrations of a method of polishing in a third embodiment.
- Figure 27 is a plan view of an example of the polishing apparatus suitable for
the methods presented above.
- Figure 28 is a perspective view of another example of the polishing apparatus
suitable for the methods presented above.
- Figure 29 is an enlarged plan view of the essential parts of the apparatus shown
in Figure 28.
- Figure 30 is a plan view of the overall structure of an example of the polishing
apparatus applicable to present invention.
Best Mode for Carrying Out the Invention
In the following, preferred embodiments will be presented
with reference to the drawings.
Figure 4 shows an example of the polishing apparatus of
the present invention. The apparatus comprises: a turntable 5 having an abrading
plate 15 of about 60 cm diameter in stead of a polishing cloth thereon; a nozzle
10 for supplying water or an active solution W without abrasive particles during
polishing. Other components such as top ring 1 for holding a wafer 4 are the same
as those in the conventional apparatus shown in Figure 1. The reason for supplying
a polishing solution W such as water or an active solution is to provide lubrication
at the sliding interface, to promote chemical reactions at the sliding interface,
and to remove heat generated by polishing for cooling. Water or active solution
W includes acid solutions with pH down to about 1, alkaline solutions with pH up
to about 12, buffer solutions, surface activators, oxidizing solutions, reducing
solution, ultrapure water, and electrolytic ionized water and the like. As an example,
the flow rate of water may be 200 ml/min. Water may be ultra-pure water so as to
exclude impurities. Wafer 4 as an object of polishing is pressed against the abrading
surface of the abrading plate 15 through an elastic mat 2 placed in the top ring
1, and rotated by the drive shaft 8. The turntable 5 with mounted abrading plate
15 is also rotated independently, and the abrading surface of the abrading plate
15 forms a sliding interface with the surface of the wafer 4 on which polishing
action takes place between the sliding and pressing surfaces.
The polishing apparatus shown in Figure 4 has an abrading
plate instead of a polishing cloth used in the conventional apparatus. But polishing
apparatus for polishing the object using the abrading plate to obtain a flat and
mirror finish, can also be used, and such types include a scroll type or cup type
other than turntable type.
The scroll type polishing is based on holding the wafer
in a wafer-holding device and an abrading plate bonded to a base disk, and the two
parts are slid in a circular and translational motion relative to each other. The
cup type polishing is based on a cup-shaped plate or a ring-shaped plate held in
a plate-holding device and the wafer is firmly attached to the base disc. The polishing
surface of an object is pressed against the abrading surface of the plate and scrolled
to produce a polishing action. In these types of apparatuses also, it is possible
to use a self-stopping function to stop polishing automatically when the irregularities
are eliminated.
Figures 5 and 6A, 6B illustrate a circular and translational
motion mechanism of a scroll type polishing apparatus. Circular (or circulative)
and translational motion means that two surfaces only produce translational motion
with circular or the like movement without changing the relative orientation. In
such a design, the abrading plate needs to be only slightly larger than the substrate
to be polished. Therefore, it is possible to produce abrading plate of highly flat
surface easily, and the drive motor can be small, and the apparatus can also be
made smaller and compact so as to save the floor space. The apparatus is comprised
of a translational table section 31 to provide circular and translational motion,
and a top ring 32 for holding a wafer 4 with its polishing surface facing downward
to press the polishing surface thereof against the abrading surface of the plate.
The translational table 31 is supported at three or more
peripheral locations by a support plate 35, extending inside in a ring-shape, provided
with a support section 36 at the top of a casing 34 housing a motor 33 inside to
support a fixed disk 37. The top surface of the support section 36 and the bottom
surface of the fixed disk 37 are provided with corresponding depressions 38, 39
spaced apart evenly in the circumferential direction, housing respective bearings
40, 41. Bearings 40, 41 are connected by a connecting member 44 whose shafts 42,
43 are separated by a distance "e", as shown in Figure 6, and whose ends are inserted
into the respective bearings. The fixed disk 37 thus undergoes a circular and translational
motion along a circle of radius "e".
The fixed disk 37 is rotated by the motor 33 whose shaft
45 has an offset drive pin 46 which is inserted in a cavity 48 through a bearing
47. The offset amount is the same as the distance "e". The motor 33 is housed in
the motor chamber 49 in the casing 34, and the shaft 45 is supported by top and
bottom bearings 50, 51, and is provided with balancers 52a, 52b to counter balance
the offset.
The fixed disk 37 has a radius which is slightly larger
than the wafer 4 by the offset amount "e", and includes two bonded disk members
53, 54. The two disk members form a space 55 between the disks for flowing water
or solution to be supplied to the polishing interface. The space 55 communicates
with the solution supply hole 56 formed on the side surface and communicates also
with a plurality of liquid outlets 57. The fixed disk 37 has an abrading plate 59
bonded to its top surface. Liquid outlets 57 formed on the abrading plate 59 correspond
to the discharge holes 58 formed on the fixed disk 37. These discharge holes 57,
58 are normally distributed evenly across the fixed disk 37 and abrading plate 59.
The top ring 32 serves as a pressing tool for the wafer
4, and is attached to the shaft 60 so as to permit tilting with respect to the polishing
surface of the wafer 4. Top ring 32 is operated by an air cylinder (not shown),
and is rotated by the drive motor via the shaft 60. The wafer 4 is attached to the
base holding section 61 of the top ring 32 with the elastic mat 62 intervening between
the two surfaces. The casing 34 has a solution recovery trough 63 attached to its
outer surface at the top.
The process of polishing using the polishing unit will
be explained below. The motor 33 is rotated to operate the fixed disk 37, and the
wafer 4 attached to the top ring 32 is pressed to the abrading surface of the abrading
plate 59 bonded to the fixed disk 37. Polishing liquid is supplied to the polishing
interface through the liquid supply hole 56, space 55 and discharge holes 57, 58,
and is delivered to the polishing interface through the grooves fabricated on the
surface of abrading plate 59.
Here, a circular and translational motion of a radius "e"
is generated between the surfaces of the abrading plate 59 and the wafer 4 so as
to produce uniform polishing on the entire surface of the wafer 4. In this case,
when the positions of the object and abrading surface are fixed, local differences
in the nature of the abrading surface will affect the polished surface, and to avoid
such an effect, the top ring 32 is slowly rotated by itself so that polishing is
not performed in the same spot.
The abrading plate used in the apparatus has a self-stopping
capability, which stops polishing automatically when the irregularities are eliminated
from the polishing surface. Abrasive particles may be an ultra-fine powder of cerium
oxide (CeO2), and the binder is a polymeric resin such as polyimide or
phenolic.
Abrasive particles may include SiO2, Al2O3,
ZrO2, MnO2 and Mn2O3, in addition to
CeO2. Binders may include other polymeric resins such as urethane, epoxy,
polyvinyl alcohol resins, in addition to polyimide or phenol resins. Choice is determined
by the nature of the films formed on the semiconductor wafer, and compatibility
of the abrasive particles with the binder.
Abrading plate has a very high hardness (extremely high
elastic coefficient), and therefore, the size of the abrasive particles directly
affects the extent of the surface damage compared with normal CMP using a polishing-pad.
For example, as shown in Figure 7B, normal polishing-pad 20 is soft compared with
an abrading plate 21 so that a vertical load will force the abrasive particles 22
into the wafer 23 while the pad 20 itself touches the wafer 23. In other words,
the pressing force is distributed over the pad so that the stress do not become
concentrated on the abrasive particles 22. In contrast, in the case of abrading
plate 21, as shown in Figure 7A, the abrading plate 21 is considerably harder than
the pad 20 so that it tends not to touch the wafer, and the pressing force is almost
totally loaded on the abrasive particles 22. In other word, the stress applied on
each abrasive particles 22 is higher than that in the CMP process, and naturally
the surface damage can be more severe.
A remedial step is to increase the number of abrasive particles
22 so that each abrasive particles 22 is applied with reduced stress. For example,
if the particle size is reduced by 1/4 to 0.5 µm from 2.0 µm, the number
of particles filling a given area increases by a 16 fold, as shown in Figures 8A,
8B, and a simple estimate is a reduction in stress of 1/16 on each abrasive particles
22. It is therefore desirable to reduce the size of the abrasive particles. The
effect of fine particle size on reducing the surface damage is more important than
in the case of normal CMP. From such a viewpoint, it is desirable that the size
of the abrasive particles be less than 2.0 µm and more preferably less than
0.5 µm.
The abrading plate is used inside the cleanroom so that
it is important not to include impurities therein. Impurities (especially metallic
substances) adversely affect the performance of semiconductor devices. Metal content
in polishing slurry has particularly severe effects on the device quality, whereas
metal oxides in the abrasive particles may also dissolve in acid or alkaline solution
to produce ions. Metallic substances in ionic states in the slurry solution can
diffuse into insulating SiO2 (oxide) surface film and reduces insulating
qualities of the film. Also, residual metallic contamination on cleaned wafers also
pose problems, because they can affect the next process and contaminate the cleanroom.
Therefore, it is desirable that the metal contents in the abrasive particles (metals
other than the main particle constituent) be kept as low as possible. For example,
in the case of CeO2, the purity is normally less than 50 %, but there
are no cases that an abrading plate uses abrasive particles of higher than 90 %
purity. For slurries which are used for normal CMP, metal group impurities, for
example Fe, are contained at a level of 60 ppm, they can remain even after washing
on the surface of semiconductor wafer. When the Fe content is limited to less than
a several ppm, normal washing is sufficient to remove the contamination. Therefore,
by using abrasive particles having more than 90 % purity (preferably higher than
94 %), contamination by metallic impurities can be avoided. Additionally, Na has
a particularly adverse effect on the device performance so that the Na concentration
in the abrasive particles should be kept below 100 ppm.
Relationship between the size of abrasive particles (CeO2)
and the severity of scratches was investigated experimentally. The abrading plates
are fabricated by using abrasive particles of CeO2 having average particle
sizes of 1.3 µm and 0.4 µm. As binder, polyimide binder is used. The abrading
plates are fabricated by dry pressure shaping method with heat treatment. The results
shows that the severity of damage (number of scratches) caused by 0.4 µm abrasive
particles was 1/10 of that caused by 1.3 µm abrasive particles. Polishing performance
was about the same for both sizes, thus indicating that finer abrasive particles
size is preferable.
It is considered that polishing is performed primarily
by the action of abrasive particles fixed in the abrading plate against the raised
regions of the wafer, as well as by the action of the free abrasive particles released
from the plate in the sliding interface. In the polishing method using abrading
plate, because the abrading plate is comparatively harder than the conventional
polishing-cloth (polishing-pad), the abrading surface of the plate will touch only
the raised regions of the wafer at a comparatively higher stress, thus, high surface
pressure applies to the raised regions. The results is that detachment of abrasive
particles occurs by the action of the raised regions of the wafer shaving the abrading
surface of the abrading plate. The particles released from the matrix of the abrading
plate will further induce polishing action on the polishing surface. When the irregularities
are eliminated, the number of released particles will become less, and because the
sliding interface is shifting along with the motions of the top ring and the turntable,
there will be less residual abrasive particles remaining in the sliding interface.
Polishing rate is thus reduced and self-stopping function of the abrading plate
is acted.
According to the polishing method by abrading plate, polishing
is carried out without a slurry solution containing a large amount of abrasive particles.
Therefore, expensive special polishing solution is not needed, and the polishing
cost can be reduced, and spent solution can be treated without problems so that
environmental problems are reduced. Also, consumable polishing cloth is not needed,
further contributing to reducing the polishing cost.
Figure 9 shows a tri-axial composition diagram in volume
percent of abrading plate, showing an optimum area of abrasive particles, binder
and porosity for producing abrading plates having a self-stopping capability, obtained
by experiments. Filled triangles represent phenol binders, filled circles represent
polyimide binders and unfilled squares represent urethane binders. Abrasive particles
are CeO2.
Experimental results show that the abrading plates made
in the proportion shown within an area B will exhibit good self-stopping capability.
That is, abrasive particles should be more than 10 % and should be less than twice
the binder volume. When the abrasive particles volume is more than twice the binder
volume, freed abrasive particles are likely to be self-generated, and the excessively
increased freed particles in the sliding interface interfere with the self-stopping
function. Also, such an abrading plate exhibits high wear, lacking in mechanical
strength. Such an abrading plate is also difficult to manufacture, because of the
tendency to form cracks during the abrading plate shaping operation. On the other
hand, when the volume of the abrasive particles is less than 10 %, released particles
are reduced thus reducing the polishing rate, and lowering throughput of manufacturing
semiconductor devices.
The volume of binder should be more than half the abrasive
particles volume and less than 60 % by volume (%) of the overall volume. When the
binder volume is less than half of the abrasive particles volume, particle-retaining
strength in the matrix is reduced and abrasive particles are more readily seld-generated
from the abrading plate, thereby losing the self-stopping function. Such an abrading
plate is prone to wear and becomes brittle. When the binder volume exceeds 60 %,
particle-retaining strength is increased too much, and little freed abrasive particles
are generated, and the polishing rate is reduced. Also, the mechanical strength
of the abrading plate becomes too high, and increases the danger of causing damages
on the surface of the semiconductor wafer.
The amount of porosity should preferably be 10~40 %. When
the porosity is less than 10 %, binder volume is too high, and causes the particle-retention
to become too strong and freed abrasive particles are not formed, and polishing
rate is reduced as discussed above to lose the self-stopping function. When the
porosity increases beyond 40 %, the mechanical strength of the abrading plate is
reduced, and the abrading plate becomes brittle, and wear resistance are lowered
as a whole. Too many abrasive particles are created and self-stopping function is
again not effective. The area bounded by B represents volume of abrasive particles
10~60 %, binder 30~60 %, and porosity 10~40 %. It is preferable that the composition
in volume be in ranges of abrasive particles 20~50 %; binder 35~55 %; and porosity
15~30 %.
Figures 10 and Figures 11A, 11B, 11C show the results of
polishing a semiconductor device patterned wafer having raised and depressed regions
with self-stopping function produced by an abrading plate made with the composition
represented by point A in Figure 9. The particles were CeO2 and the binder
was polyimide mixed in a ratio of particles : binder : porosity at 30:45:25, respectively.
As shown in these results, raised regions exhibited a height of more than 20,000
angstroms initially, and within 1 relative time unit, the height was reduced to
less than 15,000 angstroms, and this height was maintained even when polishing was
continued for another 2 time units so that the height of the raised and depressed
regions remained the same. Namely, only the raised regions are polished, and the
depressed regions are not polished. Thereby, it is easy to obtain flat surface structure
by eliminating irregularities between raised regions and depressed regions of the
semiconductor devise wafer. After then, even if polishing is continued, film thickness
is kept unchanged, the polishing process thus achieves the self-stopping function
such that material removal is automatically controlled after a level surface has
been attained. Thus, polishing time based control task becomes easier, the allowable
range of processing (the process window), is widened. The film thickness in the
depressed regions is maintained at the original thickness so that design of film
thickness is facilitated. Also, if there are some regions that are being polished
slowly, those regions which have been already polished are not subjected to further
polishing while waiting for the slow regions to catch up. When the slow regions
are polished, the overall surface attains a single level and uniform flatness.
Figure 11A~11C illustrate the changes in the profile of
the surface structure. Figure 11A shows an initial stage, Figure 11B shows middle
stage (time 1), and Figure 11C shows the final stage of polishing (time 2), respectively.
As illustrated, only the raised regions are polished in relative time 1 to produce
a level surface, which remains unchanged even when polishing is continued to time
2.
Figure 12 shows the results obtained using an abrading
plate, indicated by point C in Figure 9, that does not have the self-stopping function
with a particle : binder : porosity ratio at 50:15:35, respectively. The progress
of polishing is illustrated in Figure 13A for initial stage (time 0), Figure 13B
for middle stage (time 1), and Figure 13C for final stage (time 2), respectively.
In this case, the abrading plate is made with a low binder
volume, consequently, the abrading plate is brittle and abrasive particles are easily
released from the abrading plate shown in Figure 9. Until time 1, raised regions
are preferentially polished and the depressed regions are hardly polished. Therefore,
a level surface can be obtained easily, but polishing continues to be active even
after a level surface has been reached because of the abundance of released particles.
Therefore, at time 2, the height of the wafer is now reduced as a result of the
continued polishing. For this reason, although the irregularities are easily eliminated,
polishing is continued so that the allowable range of processing (the process window)
is narrowed, i.e., polishing control becomes much more difficult. Furthermore, because
the rate of material removal is different before and after achieving a flat surface,
it is difficult to control polishing time properly.
Figure 14 shows a polishing characteristics of a freshly
dressed (roughened) abrading plate on a blanket wafer having no fine-structures
fabricated on the surface. Polishing rate (in Å/min) is plotted on the vertical
axis and polishing time of dressed abrading plate after dressing in hours is plotted
on the horizontal axis. It can be seen that the rate of material removal by freshly
dressed (roughened) abrading plate shown in "a" is high, because of the abundance
of released abrasive particles. When such a freshly dressed abrading plate is applied
to a semiconductor device patterned wafer, raised regions of a wafer can be polished
at high speed and the irregularities can be eliminated, but polishing action will
be continued and lead to a result similar to the results shown in Figure 12. It
is clear that the self-stopping function does not work in this case. Self-stopping
means that the irregularities are eliminated and flatness is achieved, and from
this point on, further polishing will not produce further material removal, that
is, the film thickness is unchanged. This result is equivalent to the result obtained
on polishing a blanket wafer having no such patterned fine-structure. Therefore,
before using a freshly dressed abrading plate on a semiconductor device patterned
wafer, the dressed abrading plate should be conditioned using a blanket wafer to
remove abrasive particles and to moderate the initial rapid rate of material removal,
so that the self-stopping function can work effectively.
That is, before the semiconductor device patterned wafer
is polished, freshly dressed abrading plate should be treated using blanket wafers
so that the polishing process is carried out after the polishing rate has been lowered
sufficiently as indicated by "b" in the figure, thereby enabling to provide an abrading
plate exhibiting a self-stopping function shown in Figure 10.
Abrading plate may be manufactured by a dry pressure shaping
method with heating treatments involving the steps of: mixing the binder and abrasive
powder, filling a mold, forming an abrading plate (pressing and heating), cooling,
bonding to a base plate, shaving (planing) of the abrading surface. Planarity of
the finished abrading plate is about ± 100 µm but this flatness is inappropriate
to polish semiconductor device patterned wafers, because the contact with the polishing
surface is only partial and the surface cannot be processed properly. Therefore,
semiconductor wafer processing requires, for example, an abrading plate initially
dressed by a dresser having diamond particles (#100 or #200 size) electro-deposited
in a nickel base. Dressing may be carried out at 400g/cm2 for 10 minutes.
This initial operation is called abrading plate shaping. The final surface roughness
of the abrading plate for polishing semiconductor device patterned wafer is preferably
less than ±30 µm.
The abrading surface of the freshly shaped abrading plate
appears similar to one shown in Figure 15A where many abrasive particles 22 are
found. When a device patterned wafer is polished using an abrading plate having
such an abrading surface structure, polishing rate is very high as indicated by
"a" in Figure 14. Although leveling can be obtained easily, the material removal
process continues even after flatness is achieved as shown in Figures 12 and 13.
In contrast, when the residual particles 22, remaining on the freshly dressed surface
is removed, as shown in Figure 15A, a device patterned wafer is polished using an
abrading plate having a surface structure shown in Figure 15B, where the particles
have been scraped away, the rate of material removal is slower as indicated by "b"
in Figure 14. When a device patterned wafer is polished in this condition, level
surface is obtained while maintaining desirable irregularities, and after the desired
level surface is produced, the abrading plate will exhibit self-stopping function
so that it appears as though material removal has been stopped automatically.
It is thought that self-stopping effect is generated as
follows. Fine structures fabricated on a device patterned wafer surface is comprised
of many fine raised regions and depressed regions. When such a device patterned
wafer is pressed against an abrading surface of an abrading plate, the fine structure
acts like a dressing tool, and although the dressing effect is not to the extent
that is produced by diamond dresser (size of diamond particle is approximately 100~300
µm), tips of the fine-structure bite into the abrading surface of the abrading
plate and scrape out the abrasive particles, producing freed abrasive particles
through a soft dressing process. An abrading surface shown in Figure 15B can hardly
abrade the blanket wafer surface, as indicated by "b" in Figure 14. But when such
a relatively clean abrading surface is used to polish a device patterned wafer having
raised regions and depressed regions, the effect is almost the same as the abrading
plate being soft-dressed to produce an abrading surface structure similar to the
one shown in Figure 15A. The roughened abrading surface, being produced by the device
patterned wafer, can release abrasive particles which are effective in leveling
the fine-structure of the device patterned wafer, and when leveling is achieved,
the device wafer surface becomes effectively similar to that of a blanket wafer,
and the profile of the abrading plate changes to a structure similar to the one
shown in Figure 15B, which no longer produces any more released abrasive particles
and the process stops because of the self-stopping effect of the abrading plate
structure.
It should be noted that the self-stopping feature cannot
be produced in any type of abrading plates, and the effects can be different depending
on the composition of the abrading plate. Polishing characteristics for device patterned
wafer can be divided into three large categories as shown in Figures 16A, 16B and
16C. Differences in the characteristics are made clear by carrying out continuous
polishing experiments using blanket wafers with a conditioned abrading plate. Only
those abrading plates exhibiting the behavior of rapid initial polishing followed
by a lower rate of polishing will exhibit quick elimination of irregularities followed
by self-stopping effect (refer to Figure 16A). For abrading plates exhibiting high
removal rate even after the irregularities are eliminated, self-stopping effects
will not be observed (refer to Figure 16B). The abrading plates exhibiting low removal
rate from the beginning is not effected by soft dressing by semiconductor device
patterned wafer so that particles cannot be scraped out, resulting in almost no
material removal and no self-stopping effect (refer to Figure 16C). The abrading
plates that exhibit the type of polishing behavior shown in Figure 16A are found
in the compositional area denoted by B region in Figure 9. Outside of this compositional
area, abrading plates with low binder volume or high porosity volume are relatively
soft abrading plates, and their polishing characteristics are represented in Figure
16B. Abrading plates with high binder volume and low porosity volume are relatively
hard abrading plates, and their polishing characteristics are represented in Figure
16C.
To develop the self-stopping capability of the abrading
plate, it is necessary to remove residual particles from the dressed abrading plate
before it can be used for polishing a wafer. One method of eliminating the residual
abrasive particles is to condition a blanket wafer until the polishing rate stabilizes
at some lower rates. This method is based on pressing and rotating the abrading
plate against a blanket wafer chucked in a wafer carrier while flowing water during
conditioning. But the conditioning tool is not limited to a blanket wafer, and any
type of tool having a flat surface made of a hard material can be used. For example,
quartz glass substrate or ceramic substrate can be used in the same manner. Such
conditioning tools are also chucked in the wafer carrier (top ring) so that the
tool should have about the same size and thickness (less than 1 mm) as the wafers.
When thicker materials are used, it is necessary to modify the chuck by adding an
adapted chuck mechanism having an increased guide ring height, for example. Supply
of liquid during conditioning is absolutely essential, and the type of liquid, for
example, such as water should serve to cool the conditioning tool and sweep the
released particles away.
Operating parameters when using a blanket wafer, for example,
are: rotational speeds of abrading plate table/substrate at 50/35 rpm respectively;
pressing pressure for substrate at 500 g/cm2 which is equivalent to wafer
polishing surface; water flow rate at 200 ml/min; and total polishing time of 10
minutes approximately.
Other methods include a method using a brush 25, instead
of the blanket wafer, for washing the abrasive surface 15 with water (refer to Figure
17A), or a method using a brush roller 26 and water (refer to Figure 17B). These
methods are effective in removing the residual abrasive particles and producing
a suitably roughened abrading plate (involving a roughness of less than ±30
µm). Operating parameters are, for example, rotational speeds of abrading plate
table/brush at 20/12 rpm, brush pressing pressure at 200 g/cm2, water
flow rate at 200 ml/min, and a removing time of 1 minute. Brush 25 should have a
relatively soft tip made up of fibers of less than 1 mm diameter, which is rotated
and pressed against the abrading surface 15 while flowing a liquid W such as water
to remove the released abrasive particles.
Also, methods based on fluid pressure applied by a water
jet 27 (refer to Figure 17C) or ultrasonic jet 28a ejected from an ultrasonic source
28 (refer to Figure 17D) are also effective. Water jet 27 should be used at a pressure
of less than 5 kPa or more preferably less than 2 kPa to remove the residual abrasive
particles and to produce a suitably conditioned abrading plate having a roughened
surface (involving a roughness of ± 30 µm). Excessively high jet pressure
should be because it avoided not only removes the residual abrasive particles but
also fractures suitably roughened abrading surface to be smoothened, which may negate
the dressing effects by the semiconductor device patterned wafer. For the same reason,
the operating parameters such as frequency and intensity should be carefully selected
to operate an ultrasonic jet 28a.
Operating parameters for the particle removal method using
ultrasonic fluid are, for example, frequency at 20 kHz, output power at 50 W, a
conditioning time of several minutes and a flow rate at 200 ml/min. To effectively
treat the entire abrading surface, it is desirable to move the ultrasonic transducer
hone 28 to reciprocate between the center and the edge of the abrading plate 15
at a separation distance of 1 mm or less than 1 mm. Water jet such as Cabijet and
Megajet (trade name) may also be used. These methods are effective in removing the
residual abrasive particles to produce a suitably roughened surface of the abrading
plate (having a surface roughness of less than ±30 µm). Excessive treatment
may not only remove the residual released abrasive particles but also fracture suitably
roughened abrading surface of the abrading plate to be vanished.
By providing such conditioning treatment to a dressed abrading
plate, polishing rate can be stabilized for a short period of time. However, as
polishing is continued, polishing rate can sometimes gradually decrease, so that
the abrading plate may have to be re-dressed. As re-dressing (soft dressing) of
the abrading plate is carried out to reestablish moderate roughness of the abrading
surface of the abrading plate, and different from the initial dressing for shaping
the abrading surface of the abrading plate as shown before, it should be basically
carried out using less severe (soft) parameters with the pressure of less than 100
g/cm2. After such conditioning, residual particle removal is not required,
and even if it is required, short treatment time is sufficient. Re-dressing parameters,
for example, are: diamond particles of #200 size; pressure for dresser of less than
50g/cm2; and dressing time of less than 1 minute. According to this condition,
it produces an abrading plate having a surface roughness of less than several tens
of micrometers.
Next, an outline of the process for manufacturing the abrading
plate will be described. In general, the process is a dry pressure shaping accompanied
with concurrent heat treatment. This process involves a uniformly mixed powder of
abrasive particles and a binder of a given ratio, which is filled into a cavity
of a press mold. The mixture is compressed and heated to a certain pressure to produce
an abrading plate of required dimensions with concurrent heat treatment. Heat treatment
is used to soften the binder to promote adhesion to particles and formation of a
strong matrix.
Other methods include a wet method for fabricating abrading
plate. An organic solvent (for example, ethanol) is prepared in a container, and
a binder such as polyimide resin (liquid or powder) is dissolved in the organic
solvent, to which are added abrasive particles. In this example, abrasive particles,
CeO2, are added in a ratio described earlier, and the liquid mixture
is stirred with a stirring device to produce a feed mixture having uniformly dispersed
abrasive particles.
The feed liquid, having the particles uniformly distributed
in the binder, is poured into a tray and heated in a vacuum oven to drive out the
volatile liquid at 50 °C for two hours, for example, to produce a solid precursor.
The precursor is pulverized to produce a pulverized powder of binder resin adhering
to the abrasive particles. This powder is filled in a cylindrical container and
pressed from above to produce a solid preform. This pressing operation determines
the shape of the abrading plate. The compressed solid preform is heated in an oven
to soften (gel) the binder and cause it to fuse to the binder adhering to the neighboring
abrasive particles. This process produces a strong abrading plate comprised by abrasive
particles bonded to a resin matrix material.
The abrasive particles in such an abrading plate are distributed
in the matrix material containing a given amount of porosity (opening), and are
inter-connected by the binder. It is thought that the porosity or opening is formed
by air, which is incorporated in the pulverized powder during the process of pressure
shaping the solid intermediate. Therefore, the volume ratio of the porosity in the
matrix can be controlled by the compression ratio in the pressing operation.
It would be evident that, although the embodiments were
illustrated using CeO2 and polyimide or phenol resin, abrading plates
exhibiting the self-stopping property can be produced using abrasive particles and
binders that were not included in the description given.
As described above, the polishing method described above
has an advantage that only the raised regions are quickly removed initially to facilitate
planarization, but that using an abrading plate of a certain composition range,
polishing does not proceed further. However, there are cases that requires removal
of further material to reduce film thickness. Such additional material removal after
the surface has become flat cannot be carried out using the polishing method described
above. Therefore, the present method of polishing is comprised of two stages: a
first stage polishing with the abrading plate; and a second stage polishing to additionally
remove the surface material to a desired thickness.
Figures 18A, 18B are schematic illustrations of the process
of the first embodiment of the present method. The first stage polishing is shown
in Figure 18A, and is based on the polishing using the abrading plate described
above. This abrading plate has a self-stopping property that enables to reduce the
rate of material removal when the raised regions of the semiconductor device patterned
wafer are preferentially eliminated and the irregularities are eliminated by polishing
while supplying only water W from the nozzle 10. However, when it is necessary to
control the film thickness to a certain value, this abrading plate is not suitable
because further polishing does not remove the surface material, due to working of
the self-stopping function.
For this reason, first, polishing time is controlled so
as to recognize that the irregularities have been eliminated. Then, in the second
stage polishing shown in Figure 18B, additional polishing is carried out by replacing
water with a polishing slurry containing a large amount of free abrasive particles.
Slurry Q of the same type as the ones used for conventional CMP is supplied from
the nozzle 9. For example, SC-1 (trade name for the product of Cabot company), which
belongs to a colloidal silica group, is suitable. The slurry contains a large amount
of normal polishing abrasive particles, and facilitates surface material removal
at high polishing rate, as in the conventional CMP.
Figure 19 shows steps of the polishing process schematically.
The first stage is used only for planarization, and the abrading plate is used to
quickly level off the raised regions. After the irregularities are eliminated using
the abrading plate, polishing rate is reduced rapidly, so that the polishing time
in the first stage is controlled by allowing some extra time in addition to the
time required to eliminate the irregularities. The second stage polishing is aimed
to remove a specific amount of surface material, and is carried out by using the
same abrading plate with an abrasive slurry supplied from the nozzle in the polishing
interface, as shown in Figure 18B. The polishing rate is determined by the type
of abrasive slurry used, so that the desired film thickness Ax can be obtained in
a relatively short time. Because this phase of polishing is started from a flat
surface, CMP can provide uniform polishing over the entire surface of the semiconductor
wafer and a high quality uniformly polished surface can be produced.
A given thickness of residual film can be achieved by time
based control and film thickness based control. Figure 20A shows an example of time-controlled
polishing method using the abrading plate shown in Figure 18A, and the process is
continued to time T1 to produce a flat surface. Accordingly, planarization over
the entire surface is achieved. After then, supplying the slurry from the nozzle
9 as shown in Figure 18B, polishing is continued to time T2. As described above,
polishing time can be determined by the type of slurry being used, therefore, it
is possible to remove surface material while continuing polishing to a given time.
Figure 20B shows an example of film thickness based control method. By polishing
the substrate using abrading plate with the apparatus shown in Figure 18A, the polishing
results in elimination of irregularities to achieve a uniformly flat surface having
film thickness A1. Additional polishing using abrasive slurry is carried out while
monitoring the film thickness so as to obtain a film thickness A2 using the apparatus
shown in Figure 18B. Because the process is controlled by monitoring the thickness,
an accurate film thickness can be obtained.
The process of switching from polishing with "liquid not
containing abrasive particles" in the first stage polishing to polishing with "liquid
containing abrasive particles" in the second stage polishing, is operated according
to a flowchart shown in Figure 22. The process is controlled by operating the opening
and the closing of electromagnetic (em) valves X1, X2, Y1, Y2 shown in Figure 21.
For example, initially the valves are in the initial stage of opening and closing
shown in Figure 22, and the solution is circulated between the delivery piping and
the storage tanks (TK1, TK2). In the first stage, each valve is placed in the first
stage condition shown in Figure 22, and polishing is performed using only water
W supplied from the nozzle 10. The first stage is controlled based on time, so that
when time T1 shown in Figure 20A has passed, polishing is stopped. The second stage
is started after detecting that T1 has passed. The second stage polishing is performed
by supplying a slurry Q from the nozzle 9 by operating the condition of valves by
a switch so as to be placed as shown in the second stage polishing condition in
Figure 22. The time of ending the second stage polishing is controlled either by
time or film thickness, so that the process is ended when time T2 shown in Figure
20A or film thickness A2 shown in Figure 20B is obtained.
Figures 23A, 23B show the second embodiment of the polishing
method. Figure 23A shows a second stage polishing apparatus used for the first stage
polishing using the abrading plate, and Figure 23B shows a polishing apparatus having
a diamond dresser 16 added to the apparatus shown in Figure 23A. Diamond dresser
16 comprises fine diamond particles of about #200 particle size embedded in the
abrading surface of the abrading plate 15, and performs conditioning of the abrading
plate 15 using water W. As illustrated, on one location on the surface of a rotating
turntable 5, polishing of wafer W is carried out by abrading plate, while, on the
other location, dressing of the abrading plate is carried out by pressing the dresser
16 on the abrading surface of the abrading plate while supplying water W from the
nozzle 10.
The first and second stage polishing in the second embodiment
are controlled by switching a series of valves using the switching apparatus shown
in Figure 24 according to the flowchart shown in Figure 25. For example, in the
first stage, each valve and the dresser are placed in the first stage condition
shown in Figure 25. First stage polishing is performed using only water W from the
nozzle 10 by placing the condition of valves and dresser as shown in the first stage
polishing in Figure 25. The first stage is controlled based on time, so that when
time T1 shown in Figure 20A has passed, polishing is stopped. Thus, the second stage
polishing is started after detecting that T1 has passed. The second stage polishing
operation with concurrent dressing operation is performed by supplying water W from
the nozzle 10 and abrasive particles generated by dresser 16, while placing the
valves and the dresser in a second stage condition shown in Figure 25 by the switching
apparatus. General operating conditions for the dresser 16 are approximately: rotational
speed of 30 rpm; and polishing pressure of 50 g/cm2. The time of ending
the second stage polishing is controlled based on either time or film thickness,
so that the process is ended at time T2 shown in Figure 20A or when film thickness
A2 shown in Figure 20B is obtained.
Figure 26 shows the third embodiment of the polishing method
schematically, and Figure 27 shows a plan view of the apparatus. A wafer 4 that
has been performed through the first stage polishing using the abrading plate 15
shown in Figure 26A is transferred to a conventional CMP apparatus shown in Figure
26B using a polishing cloth 6 and slurry containing abrasive particles through a
conventional chemical and mechanical polishing process. This CMP operation can be
carried out using a single conventional apparatus, but it may be used in a combined
manner with the polishing apparatus comprising the abrading plate so that both may
be used in a complementary manner. Namely, because of the self-stopping function
of the abrading plate using water or chemical solution, surface material removal
will not proceed after the irregularities are eliminated in the process of polishing
even in a subsequent polishing process. On the other hand, since polishing cloth
of conventional chemical mechanical polishing has elasticity, CMP using slurry will
remove surface material from both raised regions and depressed region so that it
has a drawback that height difference is difficult to be reduced rapidly. However,
the conventional CMP has an advantage that even a flat surface can be polished at
a higher polishing rate, and a highly flat polished surface is obtainable. Therefore,
in accordance with a combination of first stage polishing using abrading plate with
water or solution without abrasive particles, and second stage polishing using a
conventional CMP with a polishing cloth and a slurry including sufficient abrasive
particles, a flat surface having residual film thickness of a desired value can
be obtained in an overall short time duration on a substrate surface having irregularities
thereon. The process can be controlled, as in the embodiments described above, by
the time based control or film thickness based control methods.
Figure 27 shows an example of an apparatus in which a polishing
apparatus 71 using an abrading plate and a polishing apparatus 72 using a polishing
cloth 6 are laterally placed in a common polishing room 78. The first apparatus
71 performs polishing using an abrading plate 15 a with a self-stopping function
while supplying water or chemical solution from the nozzle 10. The second apparatus
72 performs chemical/mechanical polishing with slurry which contains an abundant
abrasive particles supplied on the cloth 6 from the nozzle 9. In this facility,
the wafer 4 is delivered through the delivery opening 73 and is placed on a transport
table 70 disposed inside the polishing room 78, and is polished by the apparatus
71 using the abrading plate 15, and after the surface has become flat and the height
difference is eliminated, the wafer 4 is transferred to the apparatus 72 for additional
material removal through a CMP process. In the apparatus 72, an abrading plate can
be installed for additional surface removal and finish polishing. The second abrading
plate in this case should have finer abrasive particles and higher porosity ratio
than the abrading plate 15 in the first apparatus 71 so that the free abrasive particles
are more readily self-generated from the abrading surface. The hardness of the binder
of finish abrading plate should be lower than that of abrading plate 15.
Figures 28, 29 respectively show an internal perspective
view and a plan view of an apparatus 80 having a turntable having a polishing cloth
6 and an abrading plate 15 which is concentrically disposed therewith. The apparatus
80 performs polishing using the abrading plate 15, and then the top ring 1 carrying
the wafer 4 is transferred to the cloth 6 and additional surface material removal
and final polish operations are carried out by supplying slurry Q from the nozzle
(not shown).
As shown in Figures 28, 29, because of the center section
and peripheral section created by the concentric arrangement of the abrading plate
table and the cloth table, there is no need to provide two turntables even when
first and second polishing stages are involved. The apparatus is compact, and only
one motor is required for both operations. Also, as shown in the figures, to avoid
mixing of the liquids used for the abrading plate polishing and the cloth polishing,
that is, water or chemical solution and slurry, a discharge groove 81is provided
therebetween. In this case, the center section is used for the abrading plate 15
and the outer section is used for the cloth 6, but this arrangement may be reversed
so that the center section is used for the cloth 6 and the outer section is used
for the abrading plate 15. Also, the center section and the outer section may both
have the abrading plates so that surface leveling and additional material removal
can be carried out at different abrading plates as needed.
Figure 30 shows an overall view of the facility which is
suitable for an embodiment of the polishing apparatus of the present invention.
The apparatus comprises a polishing section 130 and a cleaning section 150. The
polishing section 130 is comprised by a centrally placed turntable 133 having the
abrading plate of the present invention, a polishing unit 137 having a top ring
135 disposed on one side of the table 133, a dressing unit 141 having a dressing
tool 139 and placed on the opposite side of the table 133, and a workpiece handling
device 143 placed lateral to the polishing unit 137. In the washing section 150,
two transport robots 101 movable in the direction of an arrow G are disposed in
the center region, and on one side of the robot line, primary and secondary washing
devices 155, 157 and a spin dryer (or dryer with washing capability) 159 are disposed
parallel to each other, and on the opposite side, two workpiece inverters 161, 163
are disposed parallel to each other. A cassette 165 containing unpolished wafers
is disposed in the location shown in the figure, and the transport robot 101 on
the right removes one wafer at a time and hands it over to the inverter 163, which
inverts the wafer. The inverted wafer is passed from the right robot 101 to the
left robot 101 and is transported to the workpiece handling device 143 of the polishing
section 130.
The wafer on the handling device 143 is held on the bottom
side of the top ring 135 of the polishing unit 137 moving along the dotted line,
and is transferred above the turntable 133 to be polished on the polish surface
134 of the rotating turntable 133. Polished wafer is again returned to the handling
device 143, is passed to the inverter 161 by the left robot 101, and is washed and
inverted thereby. Then, the polished wafer is washed by the primary and secondary
washing devices 155, 157 using water or chemical solution, and is spun and dried
in the spin dryer, and is returned to the original cassette 165 by the right robot
101. After the top ring 135 completes polishing the wafer the dressing unit 141
moves over to the turntable 133 following the dotted line, and presses the rotating
dressing tool 139 to the polish surface of the rotating turntable 133 to perform
conditioning of the polish surface 134. It should be mentioned that the structure
of the turntable 133 can be any of the self-turning type, scroll type or cup type.
This polishing facility can be used inside a cleanroom.
Because the polishing unit produces an abundant amount of contaminating substances,
the entire polishing apparatus should be contained in a closed housing, and the
mist and dust particles produced from the polishing section and cleaning sections
are exhausted by an exhausting device, and chemical filters are disposed in the
ceiling for supplying clean air into the room. The pressure inside the facility
is kept lower than the pressure in the surrounding region (cleanroom), so that contaminated
air, mist and dust particles would not leak outside of the facility. Abrading plates
are made of particles of high purity, and particle contamination is prevented by
washing and drying the polished wafers before returning them to the wafer cassette,
and therefore, contamination by metallic contaminants and particles is avoided and
the atmosphere in the cleanroom is not contaminated.
Industrial Applicability
The present invention provides an abrading plate having
the self-stopping capability by optimizing the proportion of abrasive particles,
binder and porosity in the abrading plate. A polishing apparatus using the abrading
plate exhibits rapid leveling of the surface, but after the surface has been leveled,
further material removal does not occur. Therefore, the process can be controlled
by adjusting the polishing duration and the surface uniformity is improved. Adopting
the first and second stage polishing method of the present invention enables to
quickly eliminate the irregularities in the first stage polishing, and, in the second
stage polishing, surface material removal can be achieved uniformly on the entire
surface by polishing under condition of high concentration of freed particles. The
combined polishing process produces a flat surface quickly while controlling the
thickness of the remaining films by removing the surface material uniformly from
the leveled wafer. The polishing method is therefore applicable to precision polishing
of semiconductor device patterned wafers.