The invention relates to a dual-stack optical data storage
medium for recording using a focused radiation beam having a wavelength &lgr;
of about 655 nm and entering through an entrance face of the medium during recording,
comprising:
- at least one substrate with present on a side thereof:
- a first recording stack L0, comprising a recordable type L0
recording layer, said first recording stack L0 having an optical reflection
value RL0 and an optical absorption value AL0 at the wavelength
&lgr;, and the recordable type L0 recording layer has a complex refractive
index ñL0&lgr; = nL0&lgr; - i*kL0&lgr;
at the wavelength &lgr; and has a thickness dL0,
- a second recording stack L1 comprising a recordable type L1
recording layer, said second recording stack L1 having an optical reflection
value RL1 and an optical absorption value AL1 at the wavelength
&lgr;, and the recordable type L1 recording layer has a complex refractive
index ñL1&lgr; = nL1&lgr;- i*kL1&lgr;
at the wavelength &lgr; and has a thickness dL1, said second recording
stack being present closer to the entrance face than the first recording stack,
- a transparent spacer layer sandwiched between the recording stacks, said transparent
spacer layer having a thickness substantially larger than the depth of focus of
the focused radiation beam.
An embodiment of an optical recording medium as described
in the opening paragraph is known from
Japanese Patent Application JP-11066622
.
Regarding the market for optical recording, it is clear
that the most important and successful format so far is a write-once format, Compact
Disk Recordable (CD-R). Although the take-over in importance by Compact Disk ReWritable
(CD-RW) has been predicted since a long time, the actual market size of CD-R media
is still at least an order of magnitude larger than for CD-RW. Furthermore the most
important parameter for drives is the maximum write speed for R-media, not for RW.
Of course, a possible shift of the market to CD-RW is still possible, e.g. because
of Mount Rainier standardization for CD-RW. However, the R-format has been proven
very attractive due to its 100% compatibility with read only compact disk (CD).
Recently the Digital Versatile Disk (DVD) has gained market
share as a medium with a much higher data storage capacity than the CD. Presently,
this format is available in a read only (ROM) and a rewritable (RW) version. Next
to the DVD ReWritable (DVD+RW) standard a new recordable (R), i.e. write once, DVD+R
standard was developed. The new DVD+R standard gets increasing attention as an important
support for DVD+RW. A possible scenario is that the end customers have become so
familiar with an optical write-once format that they might accept it more easily
than a re-writable format. Recently a new format has been introduced called Blu-ray
Disc (BD) with even a higher storage capacity. For this format also R and RW versions
will be introduced.
An issue for both the R and RW formats is the limited capacity
and therefore recording time because only single-stacked media are present. Note
that for DVD-Video, which is a ROM disk, dual layer media already have a considerable
market share. A dual-layer, i.e. dual-stack, DVD+RW disk is probably feasible. However,
it has become clear that a fully compatible disk, i.e. within the reflection and
modulation specification of the dual-layer DVD-ROM, is very difficult to achieve
and requires at least a major breakthrough for the properties of the amorphous/crystalline
phase-change materials, which are used as recording layers in e.g. DVD+RW media.
Without a full compatibility, the success of a dual-layer DVD+RW in the market is
questionable.
In order to obtain e.g. a dual-stack DVD+R medium which
is compatible with the dual-layer (=stack) DVD-ROM standard, the effective reflectivity
of both the upper L1 layer and the lower L0 layer should be
at least 18%. More generally it can be said that any new generation dual stack medium
requires a minimum effective optical reflection level Rmin in order to
meet a specification, e.g. for a dual stack BD the expected value of Rmin
is 0.04 and for a dual stack BD compatible with a single stack BD Rmin
= 0.12. Effective optical reflection means that the reflection is measured as the
portion of effective light coming back from the medium when e.g. both stacks L0
and L1 are present and focusing on L0 and L1 respectively.
The conditions, which must be imposed on the optical reflection, absorption and
transmission values of the stacks in order to meet such a specification are by far
not trivial. In
JP-11066622
nothing is mentioned about requirements with respect to optical reflection,
absorption and transmission values of the stacks. It should be noted that in this
document the normally used convention of notation of L0 and L1,
in which notation L0 is the "closest" stack, i.e. closest to the radiation
beam entrance face, has been changed: L0 now is the deepest stack, as
seen from the radiation beam entrance face, and L1 is the stack closer
to the radiation beam entrance face.
In
European Patent Application EP 1143431 A2
an optical recording medium of the type as described in the opening paragraph
is disclosed with AL0 = 12 % and RL0 = 20%.
The document
WO 02/099796 A1
used for the two-part limitation of appended claim 1 describes a dual
stack rewriteable DVD.
It is an object of the invention to provide an optical
data storage medium of the type mentioned in the opening paragraph which has an
effective optical reflection level of both the L0 stack and the L1
of more than a specified value Rmin.
This object has been achieved in accordance with the invention
by an optical storage medium, which is characterized in that AL1 ≤
1 - Rmin - √(Rmin/RL0) in which formula
Rmin = 0.18 and in that the following formulas are fulfilled:
and
kL1&lgr;≤ {&lgr;*ln[1/(Rmin + √(Rmin))]}/(4&pgr;*
dL1). For a given optical data storage medium, the effective reflection
of both recording stacks of a dual-stack disc, should always lie above a specified
minimum reflection Rmin. This implies that the effective reflection of
L1 should meet the following criterion:
For L0, the effective reflection should be
Thus, we obtain a requirement for the transmission of L1 of
Equations (1) and (3) show that the optical properties of the total dual-stack
medium are mainly defined by the optical properties of L1. The combination
of equations (1) and (3) directly defines a requirement for the allowable absorption
of L1:
The maximum AL1 that is ever allowable is obtained for maximum reflection
of L0, i.e. when RL0 = 1. In this case, also the highest possible
effective reflection from L0 is obtained. Thus we can define a maximum
for the absorption in L1 that is still allowed as follows:
The choice RL0 = 1 implies that it is impossible to write data into
L0 since no absorption of optical radiation occurs. This extreme situation
would e.g. be applicable to a dual-stack recordable-ROM disc or recordable L1,
ROM L0 disc.
In an embodiment AL1 ≤ AL0.
In order to be able to record information via optical means in L0, the
L0 stack should have a finite optical absorption at the wavelength of
the radiation beam, e.g. a laser. Since only part of the light of the recording
laser is transmitted through L1, L0 should preferably be made
more sensitive, i.e. have a higher absorption than L1, in order to keep
the required write-power within acceptable limits. For a recordable dual-layer disc
it seems natural to impose the following two conditions: (i) same effective reflection
of both layers (same signal amplitudes which is preferred from drive point-of-view)
and (ii) same effective absorption in both layers (same write-powers needed irrespective
of layer). These two boundary conditions give rise to a preferred absorption in
L1 that is given by:
Then, the preferred absorption in L0 (assuming TL0 = 0) is
given by
The next step is to recognize that the absorption in L0 and L1
is mainly determined by the thickness of the recording layer dL in L0
and L1 respectively and the absorption coefficient kL&lgr;
of the recording layer material in L0 and L1 respectively
(kL&lgr; is the imaginary part of the complex refractive index nL&lgr;).
To estimate the absorption within the recording stack the effect of a possible dual-layer
stack design is omitted, which implies the following simplifications: (i) interference
effects within the recording layer are neglected, (ii) possible absorption in additional
layers that may be present is neglected, (iii) recording layer is embedded in between
two semi-infinite media having complex refractive index n0 and n2, see Fig.5. Typically
the upper surrounding medium will be transparent (substrate for L1 and
spacer for L0) while the lower medium will be either transparent (spacer
for L1) or highly reflecting (mirror for L0). Then, the absorption
of optical power within this layer depends exponentially on both dL and
kL and is calculated to be:
&lgr; is the wavelength of the laser. The term (1+|(nL-n2)/(nL+n2)|)
in the exponent is a measure for the effective thickness increase due to the portion
of light that is reflected back at the second interface of the recording layer,
see Fig. 5. The multiplication-factor (1 - |(nL-n0)/(nL+n0)|2)
accounts for the light that is reflected at the first interface.
Typically, the L1 stack will be tuned for both
finite reflection and transmission. Then, the most dominant contribution to the
stack's absorption will be the absorption for a single-pass of light. The L0
stack will be tuned for high reflection, and the stack's absorption will be close
that for a double-pass of light.
Preferably 1.5AL1≤ AL0 ≤
2.5AL1. From Fig.4 it can be seen that for equal write-power in L0
and L1, the absorption in L0 should typically be approximately
twice that of L1. For the range of most interest, i.e. finite absorption
to achieve high T in L1 and high R in L0, the double pass
will yield approximately twice as much absorption. Thus, in order to have the absorption
of both layers in the required range, the following is valid for both layers:
From Fig.6 it can be seen that this approximation is best for the L1
type stacks, where of course interference effects play a less important role.
One effect that is not taken into account in the above
calculations is the presence of the guide grooves in the medium, which are normally
present for tracking purposes in each recording stack adjacent the recording layer.
Due to these grooves, the radiation beam is diffracted and only a part (or none)
of the diffracted light is captured by the reflection/transmission measurement setup.
Thus the diffraction appears like a kind of absorption. The diffraction is used
to generate tracking signals like push-pull and track-cross and preferably these
signals are of equal magnitude on both stacks to minimize adjustments to the servo-systems
when switching between the stacks. This in turn means that for both layers a similar
amount of light is lost in the reflection/transmission measurement. It means that
the indicated ranges of absorption and k/d range are really the upper-limit that
is allowed since the range is derived assuming no diffraction losses at all.
For the recordable type L1 recording layer having
a complex refractive index ñL1&lgr; = nL1&lgr; -
i*kL1&lgr; at the wavelength &lgr; and having a thickness dL1,
the following formula is fulfilled:
- kL1&lgr; ≤ {&lgr;*ln[1/(Rmin + √(Rmin))]}/(4&pgr;*
dL1) in which formula kL1&lgr; is the absorption coefficient
of the L1 recording layer.
For the recordable type L0 recording layer having
a complex refractive index ñL0&lgr;= nL0&lgr;- i*kL0&lgr;
at the wavelength &lgr; and having a thickness dL0, the following formula
is fulfilled:
- kL0&lgr;≤ {&lgr;*1n[1/(Rmin + √(Rmin))]}/(4&pgr;*
dL0) in which formula KL0&lgr; is the absorption coefficient
of the L0 recording layer.
It is noted that the above analysis is more accurate for
low k-values (k<1); for k>1 the presented formula becomes inaccurate although
it still can serve as a rough estimate. Further it should be noted that the definition
of the thickness dL0 and dL1 of the recording layers requires
some further explanation. It may e.g. be that the recording layer thickness in a
guide groove is different from the thickness in between guide grooves due to leveling
effects during the application of the recording layer by e.g. spincoating. Hence
the thickness of the recording layer is defined as being the thickness where the
focused radiation beam spot is present during recording and read out.
To obtain a recordable dual-stack optical data storage
medium that meets the specifications of the dual-layer (stack) DVD-ROM disc, it
is required that &lgr; is about 655 nm, Rmin= 0.18 and that KL0&lgr;
and KL1&lgr; fulfil the the requirements of equations Eq(9) and Eq(10).
It is a further object of the invention to provide a method
of manufacturing a dual-stack optical data storage medium for recording using a
focused radiation beam having a wavelength &lgr; and entering through an entrance
face of the medium during recording, the stacks of the medium having an effective
optical reflection level of more than a specified value Rmin, the medium
comprising
at least one substrate, the method comprising the steps of depositing on the at
least one substrate:
- a first recording stack L0, comprising a recordable type L0
recording layer, said first recording stack L0 having an optical reflection
value RL0 and an optical absorption value AL0 at the wavelength
&lgr;,
- a second recording stack named L1 comprising a recordable type L1
recording layer, said second recording stack L1 having an optical reflection
value RL1 and an optical absorption value AL1 at the wavelength
&lgr;, said second recording stack being present closer to the entrance face than
the first recording stack,
- a transparent spacer layer sandwiched between the recording stacks, said transparent
spacer layer having a thickness substantially larger than the depth of focus of
the focused radiation beam, the which medium has an effective optical reflection
level of both the L0 stack and the L1 of more than a specified
value Rmin.
This object has been achieved in accordance with the invention
by a method as described in the previous paragraph which is characterized in that
AL1 ≤1 - Rmin - √(Rmin/RL0)
in which formula Rmin is the minimum required effective optical reflection
value for each recording stack.
To obtain a recordable dual-stack optical data storage
medium that meets the (expected) specifications of the dual-stack Blu-ray Disc (BD),
it is required that &lgr; is about 405 nm, Rmin= 0.04 and that kL0&lgr;
and kL1&lgr; fulfil the the requirements of equations Eq(9) and Eq(10).
For a dual-stack Blu-ray Disc which is compatible with
the single layer reflection specification, it is required that &lgr; is about
405 nm, Rmin= 0.12 and that kL0&lgr; and kL1&lgr;
fulfil the requirements of equations Eq(9) and Eq(10). Preferably 0.7*dL0
< dL1 < 1.3*dL0 for the media described the last three
paragraphs.
It should be noted that the invention is not limited to
a single sided dual stack medium but that by varying substrate thicknesses e.g.
two single sided dual stack media according to the invention may be bonded together
forming a dual sided dual stack medium, which fulfils thickness requirements.
The invention will be elucidated in greater detail with
reference to the accompanying drawings, in which
Fig. 1 shows a schematic layout of a dual-stack optical
data storage medium according to the invention. The effective reflection of both
stacks is indicated.
Fig. 2 shows the maximally allowable absorption in L1
as a function of the imposed minimum effective reflectivity of both layers of the
dual-stack disc.,
Fig. 3 shows the preferred absorption in L0
and L1 compared to maximally allowable absorption in L1 as
a function of the effective reflectivity of L0 and L1.
Fig. 4 shows the ratio between optical absorption in L0
and L1 as a function of effective reflection.
Fig. 5 shows a schematic layout of the absorption of an
optical radiation beam by an absorbing recording layer, neglecting interference
effects within the recording layer.
Fig. 6 shows a comparison between calculated absorption
and approximation of Eq (9) for L1 type of stack (left) and L0
type of stack (right). Solid line: exact calculation; dashed line: approximation.
Fig. 7 shows the maximum value of allowed k versus L1-recording
layer thickness for various values of effective reflection in case of a laser wavelength
within the DVD specification.
Fig. 8 shows the range of allowed k-values as a function
of L1-recording layer thickness for a dual-stack medium that meets the
DVD specifications (laser wavelength 655 nm, Rmin = 18 %).
Fig. 9 shows the maximally allowed k-value in the case
of a DVD-compatible (for R=18%) and a BD-compatible (for R=4%) dual-layer disc.
In Fig.1 a dual-stack optical data storage medium 10 for
recording using a focused radiation beam, e.g. a laser beam 9, having a wavelength
&lgr;, is shown. The laser beam enters through an entrance face 8 of the medium
10 during recording. The medium 10 comprises substrates 1 and 7 with present on
a side thereof a first recording stack 2 named L0, having an optical
reflection value RL0 and an optical absorption value AL0 at
the wavelength &lgr; and a second recording stack 5 named L1 having
an optical reflection value RL1 and an optical absorption value AL1
at the wavelength &lgr;,
- a transparent spacer layer 4 is sandwiched between the recording stacks 2 and
5, said transparent spacer layer 4 having a thickness of 50 µm which is substantially
larger than the depth of focus of the focused laser beam 9. The absorption value
fulfils the following equation:
AL1 ≤ 1 - Rmin - √(Rmin/RL0)
in which formula Rmin is the minimum required effective optical reflection
value for each recording stack.
The first recording stack 2, comprises a recordable type
L0 recording layer 3, e.g. an azo dye or any other suitable dye. A guide
groove is present in the first substrate 1 or in the spacer layer 4, a first highly
reflective layer is present between the L0 recording layer 3 and the
substrate 1. A second substrate 7 is present with on a side thereof a second recording
stack 5 comprising a recordable type L1 recording layer 6, e.g. an azo
dye or any other suitable dye. The second L1 recording stack 5 is present
at a position closer to the entrance face 8 than the L0 recording stack
2. A second guide groove is present in the second substrate 7 or in the spacer layer
4. The first substrate 1 with L0 is attached to the substrate with L1
by means of the transparent spacer layer 4, which may act as bonding layer. Specific
suitable L0/L1 stacks designs are described below.
Embodiment 1 DVD recordable dual stack R
min
= 0.18, &lgr; = 655 nm, (layers in this order):
- Substrate 1 made of PC having a thickness of 0.60 mm
- Reflective layer of 100 nm Ag (n = 0.16-5.34i), Au, Cu or Al, or alloys thereof,
may be used as well,
- L0 recording layer 3 of an azo dye, with thickness of 80 nm, the
refractive index of the dye at a radiation beam wavelength of 655 nm is 2.24 - 0.02i.
- First semitransparent reflective layer made of Ag having a thickness of 10 nm,
Au, Cu or Al, or alloys may be used as well,
- Spacer layer 4 made of a transparent UV curable resin having having a thickness
of 50 µm,
- Second semitransparent reflective layer made of Ag having a thickness of 10
nm, Au, Cu or Al, or alloys may be used as well,
- L1 recording layer 6 of an azo dye, with thickness of 80 nm, the
refractive index of the dye at a radiation beam wavelength of 655 nm is 2.24 - 0.02i.
- Substrate 7 made of PC having a thickness of 0.58 mm
This stack design has the following reflection, absorption and transmission values:
- AL0 = 0.4
- AL1 = 0.2
- RL0 = 0.6
- RL1 = 0.2
- TL1 = 0.6
- TL0 = 0
The formula AL1 ≤ 1 - Rmin - √(Rmin/RL0)
= 1- 0.18 - √(0.18/0.6) = 0.27 has been fulfilled. Furthermore KL0&lgr;*
dL0 = 1.6 nm ≤ {&lgr;*1n[1/(Rmin + √(Rmin))]}/(4&pgr;)
= 26.4 nm and kL1&lgr;* dL1= 1.6 nm ≤ {&lgr;*ln[1/(Rmin
+ √(Rmin))]}/(4&pgr;) = 26.4 nm.
The first semitransparent reflective layer may also be
a SiO2 layer with a thickness of e.g. 20 nm; other dielectrics may be
used as well. In a different embodiment the first semitransparent reflective layer
may be absent. Furthermore, additional dielectric layers may be present between
the recording layer and the reflective and/or semitransparent reflective layers.
The second semitransparent may also be a dielectric (e.g. Si02) or semiconducting
(e.g. Si) layer. Furthermore, additional dielectric layers may be present between
the recording layer and the second semitransparent reflective layer and/or between
second semitransparent reflective layer and the spacer layer and/or between the
recording layer and the substrate 7.
The following example does not form part of the claimed
invention but represents background art that is useful for understanding the invention.
Example: BD recordable dual stack R
min
= 0.12, &lgr; = 405 nm (layers in this order):
- Substrate 1 made of PC having a thickness of 1.1 mm
- Reflective layer of 100 nm Ag (n = 0.17-2i), Au, Cu or Al, may be used as well,
- L0 recording layer 3 of an organic dye, with thickness of 50 nm,
the refractive index of the dye at a radiation beam wavelength of 405 nm is 2.4
- 0.04i.
- First transparent dielectric layer made of Si02 having a thickness of 20 nm,
other dielectrics (Si3N4, ZnS-SiO2, Al2O3, A1N) may be used as well,
- Spacer layer 4 made of a transparent UV curable resin having a thickness of
25 µm,
- L1 recording layer 6 of an organic dye, with thickness of 50 nm,
the refractive index of the dye at a radiation beam wavelength of 405 nm is 2.4
- 0.04i.
- Second transparent dielectric layer made of SiO2 having a thickness
of 20 nm, other dielectrics (Si3N4, ZnS-Si02, Al2O3, AlN) may be used as well.
- Substrate 7, in this embodiment also called cover layer, made of a transparent
UV curable resin, having a thickness of 0.075 mm.
This stack design has the following reflection, absorption and transmission values:
- AL0 = 0.6
- AL1 =0.2
- RL0 = 0.4
- RL1 = 0.2
- TL1 = 0.6
- TL0 = 0
The formula AL1 ≤ 1 - Rmin - √(Rmin/RL0)
= 1- 0.12 - √(0.12/0.4) = 0.33 has been fulfilled. Furthermore KL0&lgr;*
dL0 = 2 nm ≤ {&lgr;*1n[1/(Rmin + √(Rmin))]}/(4&pgr;)
= 24 nm and kL1&lgr;* dL1 = 2 nm ≤ {&lgr;*ln[1/(Rmin
+ √(Rmin))]}/(4&pgr;) = 24 nm
In Fig.2 a graph is drawn representing the maximum allowable
absorption in L1 AL1max as a function of a minimum effective
reflection Rmin of both recording stacks L0 and L1.
Note that the maximum achievable value of Rmin is about 0.38. This value
represents the case in which the L1 stack does not have absorbance anymore
and hence recording is not possible, while also the L0 stack has no absorption
and maximum reflection (RL0 =1).
In Fig. 3 the preferred absorption in L0 and
L1 are compared to the maximally allowable absorption in L1
as a function of the effective reflectivity of L0 and L1.
This preferred absorption graphs are representations of equations (6) and (7).
In Fig. 4 the ratio between AL0 and A
L1 is shown as a function of the effective reflectivity of L0
and L1. It can be seen that preferably this ratio is in the range 1.5
- 2.5 more preferably in the range 1.5 - 2.0.
In Fig. 5 a schematic layout of a recording layer 3, 6
in a dual stack optical data storage medium 10 is shown (see Fig. 1). The path of
an optical radiation beam is show. The absorption in L0 and L1
is mainly determined by the thickness of the recording layer dL and the
absorption coefficient kL&lgr; of the recording layer material (kL&lgr;
is the imaginary part of the complex refractive index nL&lgr;). To
estimate the absorption within the recording stack the detailed effect of a possible
dual-layer stack design is omitted, which implies the following simplifications:
(i) interference effects within the recording layer are neglected, (ii) possible
absorption in additional layers that may be present is neglected, (iii) recording
layer is embedded in between two semi-infinite media having complex refractive index
n0 and n2. Typically, the upper surrounding medium will be transparent (substrate
for L1 and spacer for L0) while the lower medium will be either
transparent (spacer for L1) or highly reflecting (mirror for L0).
Then, the absorption of the optical radiation beam within this layer depends exponentially
on both dL and kL, represented by equation (8).
In Fig.6 modeling results are presented of the absorption
as a function of the recording layer thickness. The solid line indicates the exact
calculation while the dashed line is the approximation of equation (9). Notice that
the approximation is best for the L1 stack and reasonable for the L0
stack.
In Fig. 7 the maximum allowed k value for the recording
layer of L1 is shown as a function of the recording layer thickness dL1
for various values of the Rmin.
In Fig. 8 the special case where Rmin =0.18
is drawn separately where it the area with allowed k-values has been hatched.
In Fig. 9 the same is done and the graph for BD has been
added as a comparison.
It should be noted that the above-mentioned embodiments
illustrate rather than limit the invention, and that those skilled in the art will
be able to design many alternative embodiments without departing from the scope
of the appended claims. In the claims, any reference signs placed between parentheses
shall not be construed as limiting the claim. The word "comprising" does not exclude
the presence of elements or steps other than those listed in a claim. The word "a"
or "an" preceding an element does not exclude the presence of a plurality of such
elements. The mere fact that certain measures are recited in mutually different
dependent claims does not indicate that a combination of these measures cannot be
used to advantage.
According to the invention a dual-stack optical data storage
medium for recording using a focused radiation beam having a wavelength &lgr;
is described. The beam enters through an entrance face of the medium during recording.
The medium comprises at least one substrate with present on a side thereof a first
recording stack named L0, comprising a recordable type L0
recording layer, said first recording stack L0 having an optical reflection
value RL0 and an optical absorption value AL0 at the wavelength
&lgr;, and a second recording stack named L1 comprising a recordable
type L1 recording layer, said second recording stack L1 having
an optical reflection value RL1 and an optical absorption value AL1
at the wavelength &lgr;, and a transparent spacer layer sandwiched between the
recording stacks. By fulfilling the formula AL1 ≤ 1 - Rmin
- √(Rmin/RL0) in which formula Rmin is the
minimum required effective optical reflection value for each recording stack full
compatibility is achieved with a read only (ROM) version of the medium.